Reduction of Ruthenium and Iron μ-Methylene Complexes with Hydrosilanes Producing Alkane: a Model System for Methanation via the Fischer-Tropsch Mechanism

DOI: 10.1039/c39930001670

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1670 - 1672 (1993)

Update date:2022-08-03

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Authors:

Akita, Munetaka

Oku, Tomoharu

Hua, Ruimao

Moro-oka, Yoshihiko

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Article abstract of DOI:10.1039/c39930001670

Reduction of the Ru and Fe μ-methylene complexes (2: M = Ru, R = H; 3: M = Fe, R = CH2Ph) with hydrosilanes produces alkane (RMe) by way of dinuclear hydrido-methylene and methyl intermediates as confirmed by the reaction of 9 with hydrosilanes; such a reaction sequence can be viewed as a model system for methanation via the Fischer-Tropsch mechanism.

Full text of DOI:10.1039/c39930001670

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