Reduction of Ruthenium and Iron μ-Methylene Complexes with Hydrosilanes Producing Alkane: a Model System for Methanation via the Fischer-Tropsch Mechanism

DOI: 10.1039/c39930001670

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1670 - 1672 (1993)

Update date:2022-08-03

Topics:

Authors:

Akita, Munetaka

Oku, Tomoharu

Hua, Ruimao

Moro-oka, Yoshihiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930001670

Reduction of the Ru and Fe μ-methylene complexes (2: M = Ru, R = H; 3: M = Fe, R = CH2Ph) with hydrosilanes produces alkane (RMe) by way of dinuclear hydrido-methylene and methyl intermediates as confirmed by the reaction of 9 with hydrosilanes; such a reaction sequence can be viewed as a model system for methanation via the Fischer-Tropsch mechanism.

Full text of DOI:10.1039/c39930001670

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Polymethane

Cas No:27936-85-2

R&D Labs maybe for 27936-85-2

Arromax Pharmatech Co.,Ltd

website:http://www.arromax.com

Contact:+86-0512-62959601 skype:aimmezhang

Address:Suite 401, Bldg A3, 218 Xinghu St.Suzhou Industrial Park 215123, P.R. China
Anhui Gusheng Import&Export CO.,LTD

Contact:86-551-63662296

Address:Jinzhai Road NO.162 ,hefei, china
Shenzhen Feiming Science and Technology Co,. Ltd

Contact:+86-755-85232577

Address:#B2309, Fenglin International Center ,Jixiang Road, Longcheng street, LongGang District, Shenzhen city, Guangdong province, China.
HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD

Contact:+86-571-88932183

Address:Hangzhou
Changzhou Litong Chemical Co., Ltd.

website:http://www.litonchem.com/

Contact:+86-519-86301238

Address:Laoba Rd, Hutang town Changzhou Jiangsu

Relevant to this article

Regioselective C-H chlorination: Towards the sequential difunctionalization of phenol derivatives and late-stage chlorination of bioactive compounds

Doi:10.1039/c7ra09939h
(2017)
Doi:10.1021/jo00811a600
(1971)
Distribution and fate of diethyl malonate and diisopropyl fluorophosphate on pig skin in vitro

Doi:10.1002/jps.2600771008
(1988)
Doi:10.1021/jo00810a004
(1971)
DEPROTONATION OF HYDRAZINIUM DICATIONS IN THE DIAZONIAPROPELLANE SERIES TO FORM BRIDGEHEAD IMINIUM IONS; EXTERNAL AND INTRAMOLECULAR TRAPPING

Doi:10.1039/P29840000411
(1984)
Synthesis of Itaconic Acid Ester Analogues via Self-Aldol Condensation of Ethyl Pyruvate Catalyzed by Hafnium BEA Zeolites

Doi:10.1021/acscatal.6b00561
(2016)

Article Doi