Tetrahedron Letters p. 3241 - 3244 (1995)
Update date:2022-08-11
Topics:
Atkinson, Robert S.
Fawcett, John
Russell, David R.
Williams, Paul J.
The products from aziridination of the phenyl-substituted allylic alcohols 6 and 7 with 3-acetoxyaminoquinazolinones 1 and 15 have been compared with those from aziridination of the methyl ester analogues 2, and 3: the differences in diastereoselectivities using these electron-rich and electron-deficient alkenes are ascribed to the intervention of transition states 8 and 4 respectively.
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