Journal of Organic Chemistry p. 1801 - 1811 (1986)
Update date:2022-08-10
Topics:
Lau, W.
Kochi, J. K.
The ?-complex of hexamethylbenzene (HMB) and mercuric trifluoroacetate (HgT2) is converted with high quantum yields to pentamethylbenzyl trifluoroacetate and either mercurous trifluoroacetate or metallic mercury upon irradiation of the charge-transfer absorption band.X-ray crystallography establishes the charge-transfer (CT) excitation to derive from the η2-bonding of the mercuric atom to only two of the aromatic carbons of HMB.The CT photochemistry proceeds via the radical-ion pair
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