
Tetrahedron Letters p. 1389 - 1392 (1980)
Update date:2022-08-11
Topics:
Ireland, Robert E.
Haebich, Dieter
The hetero-Diels-Alder condensation between furanoid and pyranoid exocyclic vinyl ethers establishes the spiroketal system and subsequent oxidative ring contraction leads to l.6-dioxaspiroalkane carboxylic acids.The latter are useful subunits for polyether antibiotic synthesis.
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