Tetrahedron Letters p. 8385 - 8388 (1994)
Update date:2022-08-28
Topics:
Vanelle, Patrice
Rathelot, Pascal
Maldonado, Jose
Crozet, Michel P.
The reaction of 1-(dichloromethyl)-5-nitroisoquinoline with 2-nitropropane anion which gives 1-isopropylidenemethyl-5-nitroisoquinoline as major product is shown to proceed by the consecutive SRN1 and ERC1 mechanisms.These mechanisms are confirmed by the inhibitory effects of dioxygen, p-dinitrobenzene, cupric chloride and TEMPO.
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Doi:10.1002/anie.201709515
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