Journal of the Chemical Society. Perkin transactions II p. 724 - 730 (1980)
Update date:2022-08-28
Topics:
Scaiano, Juan C.
Encinas, M. Victoria
George, Manapurathu V.
Williams, D. Lyn H.
U.v.-irradiation of o-phthalaldehyde leads to the formation of phthalide and dimeric products in varying yields and ratios depending on the solvent and reagent concentration.Laser flash photolysis studies show that the photochemistry of o-phthalaldehyde involves the intermediacy of a 1,4-biradical produced by intramolecular hydrogen transfer, and with a lifetime of 1.6 μs.Two triplet states are the precursors of the biradical; they have lifetimes of 6 and 36 ns and are assigned to different rotational conformers.The triplet reaction path is not responsible for product formation; these arise via a parallel reaction path, apparently involving the singlet state.
View MoreNINGBO YINLIANG FOREIGN TRADE CO., LTD.
Contact:+86-574-87834016 / 87898057
Address:23F NO.666JINYU ROAD,YINGZHOU DISTRICT,NINGBO.CHINA
Wuhan Konberd Biotech Co., Ltd.
Contact:+86-27-87205925
Address:NO.666, Gaoxin Road, Eastlake High-tech zone
website:http://www.shtopchem.com/
Contact:0086-0576-87776998
Address:room no 1608,xuhui business building yude road,xujiahui street, xuhui district
Hangzhou LINGEBA Technology Co., Ltd.
Contact:+0086-571-87389059
Address:Office 1-913,NewYouth Plaza, GongShu Area, HangZhou,ZheJiang,P.R.China
Shanghai PotentPharm Science and Technology Co.,Ltd
Contact:86-021-51969655
Address:Unit B, Building 18, No.300, Chuantu Rd,Pudong District, Shanghai 201202, China
Doi:10.1021/acs.orglett.5b03575
(2016)Doi:10.1039/c3cc40542g
(2013)Doi:10.1021/j100327a017
(1988)Doi:10.1016/j.ultsonch.2012.02.003
(2012)Doi:10.1007/BF00470020
(1989)Doi:10.1021/j100181a051
(1992)
