Journal of Organometallic Chemistry p. 337 - 344 (1997)
Update date:2022-08-11
Topics:
Kim, Hak-Soo
Kim, Jeong-Won
Kwon, Soon-Chul
Shim, Sang-Chul
Kim, Tae-Jeong
The reaction of [Cu(MeCN)4]PF6 with a ferrocene-containing tetraazamacrocycle 2,5,19,22-tetraaza[6,6](1,1)ferrocenophane-1,5-diene (1) gives the copper(I) complex of the type [Cu(1)]PF6 (2) which crystallizes in the orthorhombic system: P212121 (#19); a = 7.597(2) A, b = 14.805(5) A, c = 24.194(4) A; Z = 4; R = 0.080; Rw = 0,083. The geometry around the central metal is a distorted tetrahedron with two pairs of differing Cu-N bond length. This complex has demonstrated the excellent catalytic activity toward the formation of cyclic carbonates and carbamates in the presence of CO2, giving almost quantitative product yields in most reactions that have been employed.
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