Canadian Journal of Chemistry p. 1753 - 1761 (1996)
Update date:2022-08-18
Topics:
Kutney, James P.
Chen, Yong-Huang
Rettig, Steven J.
Thujone-derived cyclopropylcarbinols can cleave via three distinct pathways: the exo cleavage, the endo cleavage, and the interesting cyclopropylcarbinyl rearrangement. Factors determining which pathway is adopted under specific conditions are discussed. A short sequence leading to synthesis of the sesquiterpene (+)-β-cyperone is described.
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