Organic Letters p. 3568 - 3571 (2011)
Update date:2022-08-31
Topics:
Cai, Xiang-Hai
Bao, Mei-Fen
Zhang, Yu
Zeng, Chun-Xia
Liu, Ya-Ping
Luo, Xiao-Dong
Currently, all monoterpenoid indole alkaloids (MIAs) have been derived from strictosidine, which originates from the condensation of tryptophan with secologanin in a 1:1 ratio. However, our phytochemical research on Alstonia rostrata revealed a potential new precursor for these compounds. We isolated the alstrostines A and B, and it was determined that they were derived from tryptophan and secologanin in a 1:2 ratio, which supported the presence of a new type of MIA precursor.
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