
Bulletin of the Chemical Society of Japan p. 1181 - 1182 (1980)
Update date:2022-08-28
Topics:
Masada, Hiromitsu
Murotani, Yoshiharu
Highly pure (99-100 percent) t-butyl and t-pentyl bromides and iodides, and 3-bromo-3-ethylpentane were readily prepared in 83-95 percent yields by the reactions of the corresponding alcohols with hydrobromic or hydroiodic acid, using lithium or calcium halide.The metal halides remarkably increased the yield and the purity of the products.
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