On the Regioselectivity of 4-Nitroanisole Photosubstitution with Primary Amines. A Mechanistic and Theoretical Study

DOI: 10.1021/jo00297a059

Source and publish data:

Journal of Organic Chemistry p. 3303 - 3310 (1990)

Update date:2022-08-28

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Authors:

Cantos, Albert

Marquet, Jorge

Moreno-Manas, Marcial

Gonzales-Lafont, Angels

Lluch, Jose M.

Bertran, Juan

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Article abstract of DOI:10.1021/jo00297a059

4-Nitroanisole photoreacts with n-hexylamine and ethyl glycinate, giving rise to regioselective methoxy and nitro group photosubstitution, respectively.Mechanistic evidence indicates that the latter is produced through a S_N2³Ar^*

Full text of DOI:10.1021/jo00297a059

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