
Journal of the Chemical Society, Dalton Transactions p. 885 - 888 (1987)
Update date:2022-08-29
Topics:
Alexander, Rikki P.
Stephenson, G. Richard
The influence of substituents on the preparation of tricarbonyl(η5-cyclohexadienyl)iron(1+) salts by oxidation using thallium(III) tris(trifluoroacetate) and by hydride abstraction using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone-tetrafluoroboric acid has been examined.Hydride abstraction by thallium oxidation is superior to conventional methods and offers complementary regiocontrol in some cases.An example of hydride abstraction from a blocked tricarbonyl(η4-cyclohexadiene)iron complex is described.
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