On Phenanthrene-4,5-quinones: a Synthesis of Morphenol

DOI: 10.1039/c39840001419

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1419 - 1420 (1984)

Update date:2022-08-17

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Authors:

Hewgill, Frank R.

Stewart, Jeffery M.

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Article abstract of DOI:10.1039/c39840001419

1,3,6,8-Tetra-t-butylphenanthrene-4,5-quinone (10) has been prepared as a short-lived species in solution, and rapidly rearranges to a dienone (12) which on debutylation yields morphenol (14): the corresponding 9,10-dihydroquinone (6) crystallises as its oxepine valence isomer (7).

Full text of DOI:10.1039/c39840001419

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