Bulletin of the Chemical Society of Japan p. 420 - 422 (1987)
Update date:2022-08-29
Topics:
Itoh, Shinobu
Kato, Noboyuki
Mure, Minae
Ohshiro, Yoshiki
Kinetic studies on the oxidation of thiols by coenzyme PQQ are carried out under anaerobic conditions.A bell-shaped pH-rate profile having a maximum rate at around pKa of the thiol is observed.The rate-determining step changes between acidic and basic sides of the profile indicating the existence of at least one intermediate in the course of the reaction.
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