Tetrahedron p. 1697 - 1702 (1981)
Update date:2022-08-16
Topics:
Fauve, A.
Kergomard, A.
"Tailor-made" dicarboxylic acids and dihydroxynaphthalene-triethylamine complexes catalyse the isomerisation of Δ-5-cholestenone.The reaction is faster and of lower kinetic order than with simple bifunctional catalysts; the activation entropy is more favourable, but the activation enthalpy is higher, due possibly to steric and electronic interference, between the catalysing functions, which are absent in the corresponding isomerases.
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Doi:10.1021/jm00199a006
(1978)Doi:10.1016/S0957-4166(00)00259-7
(2000)Doi:10.1002/psc.2402
(2012)Doi:10.1016/j.poly.2005.01.014
(2005)Doi:10.1016/j.jcat.2012.05.011
(2012)Doi:10.1021/jo00314a057
(1981)
