PRESSURE DEPENDENCE OF THE PHOTOSTATIONARY trans/cis CONCENTRATION RATIO OF 4-DIMETHYLAMINO-4'-NITROAZOBENZENE. A NEW METHOD OF EVALUATING THE REACTION VOLUME

DOI: 10.1246/cl.1985.1203

Source and publish data:

Chemistry Letters p. 1203 - 1204 (1985)

Update date:2022-08-29

Topics:

Authors:

Tanaka, Tohru

Sueishi, Yoshimi

Yamamoto, Shunzo

Nishimura, Norio

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Article abstract of DOI:10.1246/cl.1985.1203

A simple method of obtaining the reaction volume by means of the photostationary state method has been proposed.The reaction volume for the cis-to-trans thermal isomerization of 4-dimethylamino-4'-nitroazobenzene in some solvents was found to be well correlated to the corresponding activation volume.

Full text of DOI:10.1246/cl.1985.1203

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