Bulletin of the Chemical Society of Japan p. 315 - 316 (1982)
Update date:2022-08-11
Topics:
Esumi, Kunio
Meguro, Kenjiro
The electron-donor property of zirconia was investigated by means of the adsorption of TCNQ.The TCNQ anin radicals were formed as a result of electron transfer to adsorbed TCNQ from the zirconia surface.The radical concentration decreased with an increase in the calcining temperatures, reached a minimum value at 700 deg C, and then increased.This behavior can be explained by a change in the electron-donor site number and the strength of the electron-donor site.
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