Tetrahedron Letters p. 7633 - 7636 (1991)
Update date:2022-08-17
Topics:
Williams, Charles R.
Harpp, David N.
When triphenylmethanesulfenyl chloride (1) is treated with thiocarbonyls, an unexpected sulfur extrusion results.The mechanism of the reaction is investigated with the aid of 19F NMR spectroscopy.Indirect evidence for a thiosulfine (10) or dithiirane (11) is presented.
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