UNEXPECTED CATALYTIC SULFUR EXTRUSION IN THE REACTION OF TRIPHENYLMETHANESULFENYL CHLORIDE WITH THIOCARBONYLS

DOI: 10.1016/0040-4039(91)80551-G

Source and publish data:

Tetrahedron Letters p. 7633 - 7636 (1991)

Update date:2022-08-17

Topics:

Authors:

Williams, Charles R.

Harpp, David N.

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Article abstract of DOI:10.1016/0040-4039(91)80551-G

When triphenylmethanesulfenyl chloride (1) is treated with thiocarbonyls, an unexpected sulfur extrusion results.The mechanism of the reaction is investigated with the aid of 19F NMR spectroscopy.Indirect evidence for a thiosulfine (10) or dithiirane (11) is presented.

Full text of DOI:10.1016/0040-4039(91)80551-G

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