LOW TEMPERATURE EQUILIBRATION OF CYCLOPROPANES BY LEWIS ACID CATALYSIS

DOI: 10.1016/S0040-4039(00)81506-3

Source and publish data:

Tetrahedron Letters p. 715 - 718 (1983)

Update date:2022-08-28

Topics:

Authors:

Reissig, Hans-Ulrich

Boehm, Ingrid

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Article abstract of DOI:10.1016/S0040-4039(00)81506-3

Under the influence of Lewis acids the cis/trans-equilibration of methyl 2-trimethyl-siloxy cyclopropanecarboxylates occurs even at -78 deg C.It involves the heterolytic cleavage of a C-C bond and seems to be governed by steric effects.

Full text of DOI:10.1016/S0040-4039(00)81506-3

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