Tetrahedron Letters p. 715 - 718 (1983)
Update date:2022-08-28
Topics:
Reissig, Hans-Ulrich
Boehm, Ingrid
Under the influence of Lewis acids the cis/trans-equilibration of methyl 2-trimethyl-siloxy cyclopropanecarboxylates occurs even at -78 deg C.It involves the heterolytic cleavage of a C-C bond and seems to be governed by steric effects.
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