Photochemical and Thermal Rearrangement of Oxaziridines. Experimental Evidence in Support of the Stereoelectronic Control Theory

DOI: 10.1021/ja00378a024

Source and publish data:

Journal of the American Chemical Society p. 3929 - 3934 (1982)

Update date:2022-08-22

Topics:

Authors:

Lattes, Armand

Oliveros, Esther

Riviere, Monique

Belzecki, Czeslaw

Mostowicz, Danuta

et al. et al.

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Article abstract of DOI:10.1021/ja00378a024

The irradiation of an optically pure isomer of a spirooxaziridine, (2R,αS)-6(e)-tert-butyl-2-(α-methylbenzyl)-1,2-oxazaspiro<2.5>octane, gave a single lactam, (5S,αS)-5-tert-butyl-1-(α-methylbenzyl)hexahydro-2-azepinone.The absolute configurations of thes

Full text of DOI:10.1021/ja00378a024

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