Journal of the Chemical Society. Chemical communications p. 990 - 992 (1984)
Update date:2022-08-15
Topics:
Battye, Peter J.
Jones, David W.
The alkoxides (1a - e) undergo accelerated 1,5-shifts in hexamethylphosphoric triamide (HMPA) at 20 deg C, and the alkoxides (6a - c) rearrange similarly in HMPA at 80 - 95 deg C; the stereospecificity of the rearrangements and the exclusive formation of 2,2-disubstituted indanones (8) from (6) testify to the concerted nature of these shifts.
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