On the Mechanism of the Reduction of α-Halo Ketones by 1,3-Dimethyl-2-phenylbenzimidazoline. Reduction by a SET-Hydrogen Atom Abstraction Chain Mechanism

DOI: 10.1021/jo00277a020

Source and publish data:

Journal of Organic Chemistry p. 3842 - 3846 (1989)

Update date:2022-08-10

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Authors:

Tanner, Dennis D.

Chen, Jian Jeffrey

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Article abstract of DOI:10.1021/jo00277a020

A series of α-halocarbonyl compounds are dehalogenated by 1,3-dimethyl-2-phenylbenzimidazoline (DMBI) to give their corresponding carbonyl compounds.Contrary to the original proposal, the mechanism for these reductions was shown to proceed via a free-radi

Full text of DOI:10.1021/jo00277a020

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