Attemted Functionalisation of a Mononuclear Barium Complex of a 24-Membered Bibracchial Tetraimine Schiff-base Macrocycle derived from Tris(2-aminoethyl)amine using Salicylaldehyde

DOI: 10.1039/DT9950000765

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 765 - 770 (1995)

Update date:2022-08-17

Topics:

Authors:

Bailey, Neil A.

Barbarin, Cecilia O. Rodriguez de

Fenton, David E.

Hellier, Paul C.

Hempstead, Paul D.

et al. et al.

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Article abstract of DOI:10.1039/DT9950000765

Functionalisation of a mononuclear barium complex of a 24-membered bibracchial tetraimine Shiff-base macrocycle (L¹) derived from the barium-templated cyclocondensation of 2,6-diacetylpyridine and tris(2-aminoethyl)amine was attempted using salicylaldehyde.The reaction leads to the isolation of the tripodal ligand tris<2-(salicylideneamino)ethyl>amine (L²) and the complex BaL2²(CLO4)2.The crystal structures of the parent macrocyclic complex, 1>2(2-) 1/c (no. 14), a = 11.755(7), b = 21.733(17), c = 15.621(15) Angstroem, β = 90.50(7) deg, Z = 4>, and BaL2²(CLO4)2 1/c (<*>, no. 14), a = 12.299(15), b = 9.530(15), c = 25.798(32) Angstroem, β = 108.679(9) deg, Z =2> have been determined.

Full text of DOI:10.1039/DT9950000765

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