1835-49-0Relevant articles and documents
BORON OR ALUMINUM COMPLEXES
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Page/Page column 23, (2011/08/02)
The present invention relates to boron and aluminum complexes, to the preparation thereof, and to the use thereof for solubilizing ionic compounds. The complexes have one of the following formulae: in which D represents B or Al; R1 represents R, RF, NO2, CN, C(═O)OR, RSO2, or RFSO2; —X1—, —X2—, —X3— and X4 each represent a divalent group >C═O, >C═NC≡N, >C═C(C≡N)2, >CR2R3 or >SO2; —Y1—, —Y2— and —Y3— each represent a divalent group —O—, >N(C≡N), >N(CORF), >N(SO2R4), >NR4, >N(COR4) or >N(SO2RF); R, R2 and R3 each represent H, an alkyl group, an aryl group, an alkylaryl group, an arylalkyl group, an oxaalkyl group or an alkenyl group; R4 represents an alkyl group, an aryl group, an alkylaryl group, a heteroaryl group, an arylalkyl group, an oxaalkyl group, an alkenyl group or an RFCH2— group; RF is a perfluoroalkyl group, a partially fluorinated alkyl group, or a partially or totally fluorinated phenyl group; each of the R′2 and R′3 groups represents R or F.
Synthesis of perfluoro[2.2]paracyclophane
Dolbier Jr., William R.,Xie, Puhui,Zhang, Lianhao,Xu, Wei,Chang, Ying,Abboud, Khalil A.
, p. 2469 - 2472 (2008/09/19)
(Chemical Equation Presented) A synthesis of perfluoro[2.2]paracyclophane has been sought ever since the partially fluorinated octafluoro[2.2]- paracyclophane (AF4) was prepared and its chemistry studied. This compound has now been prepared in 39% yield from the precursor, 1,4-bis(chlorodifluoromethyl) -2,3,5,6-tetrafluorobenzene by its reaction with Zn when heated in acetonitrile at 100°C. Two preparations of the precursor, first from 1,4-dicyano-2,3,5,6- tetrachlorobenzene and an improved method beginning from 1,2,4,5- tetrachlorobenzene, are also described as are key comparisons to our related synthesis of AF4.
A new route to 2,3,5,6-tetrafluoroterephthal aldehyde and its chemical transformation
Zhu, Shizheng,Zhao, Jingwei,Cai, Xian
, p. 451 - 454 (2007/10/03)
The title compound was prepared from commercial available and cheaper starting material terephthalolyl chloride by six-step reaction sequence in total 40% yield. Its chemical transformations were also studied.
