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608-80-0

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608-80-0 Usage

General Description

Cyclohexane is a colorless, flammable liquid with a mild, pleasant odor. It is a cyclic hydrocarbon with the chemical formula C6H12, and is commonly used as a solvent in various industrial applications, including in the manufacturing of pharmaceuticals, adhesives, and insecticides. It can also be found in consumer products such as paint and varnish removers, and in the production of nylon. Cyclohexane is relatively stable and non-reactive, and it is considered to be of low toxicity, although prolonged exposure to high levels of the chemical can cause irritation to the skin, eyes, and respiratory system. It is important to handle and store cyclohexane safely in order to prevent potential health and environmental risks.

Check Digit Verification of cas no

The CAS Registry Mumber 608-80-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 6,0 and 8 respectively; the second part has 2 digits, 8 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 608-80:
(5*6)+(4*0)+(3*8)+(2*8)+(1*0)=70
70 % 10 = 0
So 608-80-0 is a valid CAS Registry Number.
InChI:InChI=1/C6H6O6/c7-1-2(8)4(10)6(12)5(11)3(1)9/h7-12H

608-80-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Hexahydroxybenzene

1.2 Other means of identification

Product number -
Other names Benzenehexol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:608-80-0 SDS

608-80-0Synthetic route

D-myo-inositol
87-89-8

D-myo-inositol

benzenehexol
608-80-0

benzenehexol

Conditions
ConditionsYield
With nitric acid
dodecahydroxycyclohexane
54890-03-8

dodecahydroxycyclohexane

benzenehexol
608-80-0

benzenehexol

Conditions
ConditionsYield
With hydrogenchloride; tin(ll) chloride
tetrahydroxy-1,4-quinone
319-89-1

tetrahydroxy-1,4-quinone

benzenehexol
608-80-0

benzenehexol

Conditions
ConditionsYield
With hydrogenchloride; tin(ll) chloride
With hydrogenchloride; tin(ll) chloride for 1h; Heating;
With hydrogenchloride; tin(ll) chloride In water for 1h; Heating;
With titanium trifluoromethansulfonate; trifluorormethanesulfonic acid; hydrogen fluoride In water at 22℃; Kinetics;
tetrahydroxy-1,4-quinone
319-89-1

tetrahydroxy-1,4-quinone

A

benzenehexol
608-80-0

benzenehexol

B

1-benzylnicotinamide chloride
5096-13-9

1-benzylnicotinamide chloride

Conditions
ConditionsYield
With hydrogenchloride; 1-Benzyl-1,4-dihydronicotinamide 1) MeCN-H2O, room temp.; Yield given. Multistep reaction;
rhodizonic acid
118-76-3

rhodizonic acid

A

benzenehexol
608-80-0

benzenehexol

B

1-benzylnicotinamide chloride
5096-13-9

1-benzylnicotinamide chloride

Conditions
ConditionsYield
With hydrogenchloride; 1-Benzyl-1,4-dihydronicotinamide 1) MeCN-H2O, room temp.; Multistep reaction;
tetrahydroxy-1,4-quinone
319-89-1

tetrahydroxy-1,4-quinone

hydrogen sulfide
7783-06-4

hydrogen sulfide

benzenehexol
608-80-0

benzenehexol

tetrahydroxy-1,4-quinone
319-89-1

tetrahydroxy-1,4-quinone

hydrogen iodide
10034-85-2

hydrogen iodide

benzenehexol
608-80-0

benzenehexol

hydrogenchloride
7647-01-0

hydrogenchloride

tetrahydroxy-1,4-quinone
319-89-1

tetrahydroxy-1,4-quinone

SnCl2

SnCl2

benzenehexol
608-80-0

benzenehexol

hydrogenchloride
7647-01-0

hydrogenchloride

tetrahydroxy-1,4-quinone
319-89-1

tetrahydroxy-1,4-quinone

tin

tin

benzenehexol
608-80-0

benzenehexol

tetrahydroxy-1,4-quinone
319-89-1

tetrahydroxy-1,4-quinone

sulfuric acid
7664-93-9

sulfuric acid

zinc

zinc

benzenehexol
608-80-0

benzenehexol

2,3,5,6-tetrahydroxy-benzoquinone-(1,4)

2,3,5,6-tetrahydroxy-benzoquinone-(1,4)

benzenehexol
608-80-0

benzenehexol

Conditions
ConditionsYield
With hydrogenchloride; tin
With hydrogenchloride; tin(ll) chloride auf Siedetemperatur;
With ethanol; hydrogen iodide
carbon oxide potassium

carbon oxide potassium

benzenehexol
608-80-0

benzenehexol

Conditions
ConditionsYield
With hydrogenchloride
cyclohexanehexon octahydrate

cyclohexanehexon octahydrate

benzenehexol
608-80-0

benzenehexol

Conditions
ConditionsYield
With water; iron(II) sulfate; platinum Hydrogenation;
With hydrogenchloride; tin
hexaketocyclohexane
527-31-1

hexaketocyclohexane

diluted aqueous FeSO4-solution

diluted aqueous FeSO4-solution

platinum

platinum

benzenehexol
608-80-0

benzenehexol

Conditions
ConditionsYield
Hydrogenation;
hydrogenchloride
7647-01-0

hydrogenchloride

hexaketocyclohexane
527-31-1

hexaketocyclohexane

tin

tin

benzenehexol
608-80-0

benzenehexol

D-myo-inositol
87-89-8

D-myo-inositol

nitric acid
7697-37-2

nitric acid

A

benzenehexol
608-80-0

benzenehexol

B

croconic acid
488-86-8

croconic acid

C

rhodizonic acid
118-76-3

rhodizonic acid

D

2.3.5.6-tetrahydroxy-benzoquinone-1.4)

2.3.5.6-tetrahydroxy-benzoquinone-1.4)

dodecahydroxycyclohexane
54890-03-8

dodecahydroxycyclohexane

hydrogen trichloro-stannate(II)

hydrogen trichloro-stannate(II)

benzenehexol
608-80-0

benzenehexol

rhodizonic acid
118-76-3

rhodizonic acid

benzenehexol
608-80-0

benzenehexol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 70 percent / 1-benzyl-1,4-dihydronicotinamide / acetonitrile; H2O / Ambient temperature
2: 1) 1-benzyl-1,4-dihydronicotinamide, 2) aq. HCl / 1) MeCN-H2O, room temp.
View Scheme
K salt of hexahydroxybenzene

K salt of hexahydroxybenzene

benzenehexol
608-80-0

benzenehexol

Conditions
ConditionsYield
With HCl; H2O decompn. with H2O, handling with dild.HCl;
With hydrogenchloride; water decompn. with H2O, handling with dild.HCl;
3-oxaoctanoyl chloride
108345-45-5

3-oxaoctanoyl chloride

benzenehexol
608-80-0

benzenehexol

hexakis<(3-oxaoctanoyl)oxy>benzene

hexakis<(3-oxaoctanoyl)oxy>benzene

Conditions
ConditionsYield
at 110℃; for 12h;99%
4-oxaoctanoyl chloride
4244-62-6

4-oxaoctanoyl chloride

benzenehexol
608-80-0

benzenehexol

hexakis<(4-oxaoctanoyl)oxy>benzene
108345-39-7

hexakis<(4-oxaoctanoyl)oxy>benzene

Conditions
ConditionsYield
at 110℃; under 100 Torr; for 12h;87%
benzenehexol
608-80-0

benzenehexol

4'-dimethylthexylsilyloxy-biphenyl-4-carboxylic acid
189456-61-9

4'-dimethylthexylsilyloxy-biphenyl-4-carboxylic acid

C132H162O18Si6

C132H162O18Si6

Conditions
ConditionsYield
With (2-chloropropyl)dimethylamine hydrochloride; 4-(dimethylamino)pyridinium tosylate In dichloromethane; N,N-dimethyl-formamide at 20℃; for 2h;70%
With 4-(dimethylamino)pyridinium tosylate; diisopropyl-carbodiimide In dichloromethane; N,N-dimethyl-formamide at 20℃; for 2h;70%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

benzenehexol
608-80-0

benzenehexol

hexakis(trimethylsilyloxy)benzene
29207-52-1

hexakis(trimethylsilyloxy)benzene

Conditions
ConditionsYield
With triethylamine In toluene at 20℃; for 12h;65%
benzenehexol
608-80-0

benzenehexol

3-Pentylsulfanyl-propionyl chloride

3-Pentylsulfanyl-propionyl chloride

hexakis<(3-thiaoctanoyl)oxy>benzene
108345-42-2

hexakis<(3-thiaoctanoyl)oxy>benzene

Conditions
ConditionsYield
at 110℃; for 12h;64%
tetrahydrofuran
109-99-9

tetrahydrofuran

phosgene
75-44-5

phosgene

benzenehexol
608-80-0

benzenehexol

hexahydroxybenzene triscarbonate

hexahydroxybenzene triscarbonate

Conditions
ConditionsYield
for 8h; Heating;47.2%
benzenehexol
608-80-0

benzenehexol

A

tetrahydroxy-1,4-quinone
319-89-1

tetrahydroxy-1,4-quinone

B

(RS)-methyl mandelate
4358-87-6

(RS)-methyl mandelate

Conditions
ConditionsYield
With methyl 2-oxo-2-phenylacetate In water; acetonitrile Ambient temperature;A 37%
B 40%
benzenehexol
608-80-0

benzenehexol

5-oxaoctanoyl chloride
108345-46-6

5-oxaoctanoyl chloride

hexakis<(5-oxaoctanoyl)oxy>benzene
108345-40-0

hexakis<(5-oxaoctanoyl)oxy>benzene

Conditions
ConditionsYield
In decalin at 120℃; for 12h;23%
n-hexyl chloroformate
6092-54-2

n-hexyl chloroformate

benzenehexol
608-80-0

benzenehexol

hexakis<(2-oxaoctanoyl)oxy>benzene
108345-37-5

hexakis<(2-oxaoctanoyl)oxy>benzene

Conditions
ConditionsYield
at 120℃; for 8h;22%
benzenehexol
608-80-0

benzenehexol

2-methoxyoctanoyl chloride
108345-47-7

2-methoxyoctanoyl chloride

hexakis<(2-methoxyoctanoyl)oxy>benzene
108345-43-3

hexakis<(2-methoxyoctanoyl)oxy>benzene

Conditions
ConditionsYield
With pyridine In decalin at 80 - 105℃; for 24h;15%
benzenehexol
608-80-0

benzenehexol

6-methoxyhexanoyl chloride
41639-69-4

6-methoxyhexanoyl chloride

hexakis<(7-oxaoctanoyl)oxy>benzene
108345-41-1

hexakis<(7-oxaoctanoyl)oxy>benzene

Conditions
ConditionsYield
at 110℃; for 7h;14%
benzenehexol
608-80-0

benzenehexol

hexamethoxy-benzene
22015-34-5

hexamethoxy-benzene

Conditions
ConditionsYield
With methanol
pyridine
110-86-1

pyridine

para-chlorotoluene
106-43-4

para-chlorotoluene

benzenehexol
608-80-0

benzenehexol

hexakis-p-toluoyloxy-benzene

hexakis-p-toluoyloxy-benzene

butanoic acid anhydride
106-31-0

butanoic acid anhydride

benzenehexol
608-80-0

benzenehexol

hexakis-butyryloxy-benzene
20129-67-3

hexakis-butyryloxy-benzene

Conditions
ConditionsYield
With zinc
2-methylbutanoic anhydride
1519-23-9

2-methylbutanoic anhydride

benzenehexol
608-80-0

benzenehexol

hexakis-(2-methyl-butyryloxy)-benzene

hexakis-(2-methyl-butyryloxy)-benzene

n-heptanoic anhydride
626-27-7

n-heptanoic anhydride

benzenehexol
608-80-0

benzenehexol

Benzene-hexa-n-heptanoate
65201-70-9

Benzene-hexa-n-heptanoate

pentanoic anhydride
2082-59-9

pentanoic anhydride

benzenehexol
608-80-0

benzenehexol

benzene-hexa-n-pentanoate
65201-68-5

benzene-hexa-n-pentanoate

undecanoic acid anhydride
2082-77-1

undecanoic acid anhydride

benzenehexol
608-80-0

benzenehexol

hexakis-undecanoyloxy-benzene

hexakis-undecanoyloxy-benzene

Conditions
ConditionsYield
at 230 - 250℃;
benzenehexol
608-80-0

benzenehexol

3,5-dihydroxyphenol
108-73-6

3,5-dihydroxyphenol

Conditions
ConditionsYield
With sodium amalgam; water unter Wasserstoff auf dem Dampfbad;
With water; platinum at 50 - 55℃; Hydrogenation;
benzenehexol
608-80-0

benzenehexol

tetrahydroxy-1,4-quinone
319-89-1

tetrahydroxy-1,4-quinone

Conditions
ConditionsYield
With air; sodium carbonate man zersetzt das entstandenen Natriumsalz durch Kochen mit verd.Salzsaeure;
With air; water
With air; ethanol
benzenehexol
608-80-0

benzenehexol

D-myo-inositol
87-89-8

D-myo-inositol

Conditions
ConditionsYield
With water; hydrogen; palladium at 50 - 55℃;
With ethanol; nickel at 125℃; under 95616 Torr; Hydrogenation;
With water; palladium at 20℃; Hydrogenation.sowie bei 55grad;
benzenehexol
608-80-0

benzenehexol

cis-inositol
576-63-6

cis-inositol

Conditions
ConditionsYield
With ethanol; nickel at 125℃; under 95616 Torr; Hydrogenation;
benzenehexol
608-80-0

benzenehexol

cis-quercitol
527-39-9

cis-quercitol

Conditions
ConditionsYield
With ethanol; nickel at 120 - 140℃; under 110326 Torr; Hydrogenation;
benzenehexol
608-80-0

benzenehexol

myo-inositol
488-59-5

myo-inositol

Conditions
ConditionsYield
With ethanol; nickel at 125℃; under 95616 Torr; Hydrogenation;
benzenehexol
608-80-0

benzenehexol

1-deoxy-scyllo-inositol
527-42-4

1-deoxy-scyllo-inositol

Conditions
ConditionsYield
With ethanol; nickel at 120 - 140℃; under 110326 Torr; Hydrogenation;
benzenehexol
608-80-0

benzenehexol

dodecahydroxycyclohexane
54890-03-8

dodecahydroxycyclohexane

Conditions
ConditionsYield
With nitric acid
With chlorine
benzenehexol
608-80-0

benzenehexol

acetic anhydride
108-24-7

acetic anhydride

hexaacetylhexahydroxybenzene
20129-65-1

hexaacetylhexahydroxybenzene

Conditions
ConditionsYield
With sodium acetate; zinc
With sodium acetate

608-80-0Relevant articles and documents

Synthesis and self-assembly of a heteroarm star amphiphile with 12 alternating arms and a well-defined core

Teng, Jing,Zubarev, Eugene R.

, p. 11840 - 11841 (2003)

We report on a stepwise synthesis of a heteroarm starlike amphiphile containing 12 alternating arms (six polystyrene and six poly(acrylic acid)) connected to a hexabiphenyl aromatic core. The synthesis does not involve polymerization, and only commercially available precursors are used. Most importantly, this amphiphile undergoes self-assembly into spherical and wormlike cylindrical micelles in aqueous and methanol solutions, and forms reverse 1D micellar structures in chloroform. This remarkable morphological diversity of the reported amphiphile 1 is believed to be a direct consequence of its well-defined molecular architecture. Copyright

Hypovalent titanium and Ti(II)-Ti(III) interconversions

Dhar, Basab Bijayi,Gould, Edwin S.

experimental part, p. 1616 - 1619 (2010/06/20)

Treatment of pink titanium(iii) triflate (0.045 M) with HF in triflic acid (CH3SO3H) converts Ti(iii) rapidly to a 1:1 mixture of TiIV and green TiII: (2 TiIII + 4 HF → TiF4 + TiII + 4 H+). This disproportionation is half complete when [HF] added is 0.027 M. Substituted 1,4-benzoquinones are reduced rapidly by Ti(iii) in the absence of fluoride, yielding straightforward logarithmic curves, but reactions of the same quinones with Ti(ii) in fluoride media exhibit more complex profiles, the major portions of which are zero order in oxidant. These reactions are strongly catalyzed by added Ti(iv). Analyses of complex curves are consistent with a reaction sequence initiated by Ti(ii)-Ti(iv) disproportionation, forming Ti(iii), which reacts with the quinone, yielding the quinhydrone, QH. The latter is rapidly reduced by Ti(ii). Values of rate constants obtained from these analyses are in agreement with those for reductions of quinones by Ti(iii), in the absence of fluoride. The Royal Society of Chemistry 2010.

REDUCTION OF METHYL BENZOYLFORMATE BY REDUCED NICOTINAMIDE ADENINE DINUCLEOTIDE MODEL IN THE PRESENCE OF RHODIZONIC ACID

Endo, Takeshi,Takada, Tadayoshi,Okawara, Makoto

, p. 615 - 618 (2007/10/02)

The reduction of rhodizonic acid (RA) with 1-benzyl-1,4-dihydronicotinamide (BNAH; NADH model) was carried out at room temperature to obtain tetrahydroxy-p-quinone (THQ) and hexahydroxybenzene (HHB) by two-electron and four-electron reductions, respectively.The reduction of methyl benzoylformate with BNAH proceded smoothly in the presence of RA, although it could not be reduced at all without RA.

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