Enantiodifferentiating photoisomerization of 1Z and 2ZZ sensitized by chiral sensitizer 3a–c
Discontinuous pressure effect upon enantiodifferentiating photosensitized isomerization of cyclooctene
Scheme 1
In the present study, we employed a newly developed high-pressure vessel and examined the enantiodifferentiating photo-isomerizations of 1Z and a new substrate, (Z, Z)-cycloocta-1,5-diene (2ZZ), at much higher pressures for further elucidation of the pressure effect upon asymmetric photosensitization.
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