Dimethyltin(IV) dichloride and dibutyltin(IV) dichloride

July 08, 2024

• Title:       

  Dimethyltin(IV) dichloride and dibutyltin(IV) dichloride

• Image Source:

  Reactivity of diorganotin(IV) dichlorides towards N, P, and O donor ligands: Crystal structure of [SnMe2Cl2(phendione)]

• Mark:

  Scheme 4

• Associated context:

  This ligand exhibits a number of coordination modes which have been extensively studied [20–22]. Dimethyltin (CAS 23120-99-2) (IV) dichloride and dibutyltin (CAS 1002-53-5) (IV) dichloride reacted with dppap to give the complexes [SnR₂Cl₂(dppap)] [R = Me (7), Bu (8)] in solution (Scheme 4).