Kinetic profile for Cr-catalyzed hydrogenation of 1a
Chromium- and Cobalt-Catalyzed, Regiocontrolled Hydrogenation of Polycyclic Aromatic Hydrocarbons A Combined Experimental and Theoretical Study
Figure 3
The initial rate (Δ[2a]/Δt) against the initial concentration of 1a ranging from 0.04 to 0.26 M showed a zero-order dependence of the initial rate on the concentration of 1a under Cr catalysis, indicating that anthracene may not be involved in the rate-determining step of the reaction or at least in the early stage of the hydrogenation (Figure 3a).
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