Treatment of a suspension of [Cp*IrCl2]2  in methanol

August 15, 2024

• Title:       

  Treatment of a suspension of [Cp*IrCl₂]₂  in methanol

• Image Source:

  Multialkylation of aqueous ammonia with alcohols catalyzed by water-soluble CpIr-ammine complexes

• Mark:

  Picture 1

• Associated context:

  Treatment of a suspension of [Cp*IrCl₂]₂ (CAS 12354-85-7) in methanol (CAS 67-56-1) with aqueous ammonia (28%) gave a new dicationic complex having ammine ligands, [Cp*Ir(NH₃)₃][Cl]₂ (1) in 94% yield (eq 1).