Welcome to LookChem.com Sign In|Join Free

Cas Database

124-41-4

124-41-4

Identification

  • Product Name:Sodium methanolate

  • CAS Number: 124-41-4

  • EINECS:204-699-5

  • Molecular Weight:54.024

  • Molecular Formula: CH3NaO

  • HS Code:2905.19 Oral rat LD50: 2037 mg/kg

  • Mol File:124-41-4.mol

Synonyms:Methanol,compounds,sodium salt;Sodium methylate-methanol solution;High pure pharmaceutical solid sodium methoxide;Sodium Methoxide (28% in methanol);Sodium methoxide (liquid and solid);Sodium methoxide-methanol;Sodiummethoxide;solid Sodium Methylate;Sodium methoxide; ( Sodium Methylate);

Post Buying Request Now
Entrust LookChem procurement to find high-quality suppliers faster

Safety information and MSDS view more

  • Pictogram(s):FlammableF,ToxicT,CorrosiveC

  • Hazard Codes:F,T,C

  • Signal Word:Danger

  • Hazard Statement:H251 Self-heating; may catch fireH314 Causes severe skin burns and eye damage

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
  • Delivery
  • Purchase
  • Manufacture/Brand:AK Scientific
  • Product Description:Sodiummethanolate
  • Packaging:1kg
  • Price:$ 129
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Alfa Aesar
  • Product Description:Sodium methoxide, ca 25% w/w in methanol
  • Packaging:2500ml
  • Price:$ 83.9
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Alfa Aesar
  • Product Description:Sodium methoxide, ca 30% w/w in methanol
  • Packaging:2500ml
  • Price:$ 94.2
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Alfa Aesar
  • Product Description:Sodium methoxide, 98%
  • Packaging:2000g
  • Price:$ 111
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Alfa Aesar
  • Product Description:Sodium methoxide, 98%
  • Packaging:100g
  • Price:$ 30.5
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Alfa Aesar
  • Product Description:Sodium methoxide, ca 25% w/w in methanol
  • Packaging:500ml
  • Price:$ 32.6
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Alfa Aesar
  • Product Description:Sodium methoxide, ca 30% w/w in methanol
  • Packaging:500ml
  • Price:$ 37.2
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Alfa Aesar
  • Product Description:Sodium methoxide, 98%
  • Packaging:500g
  • Price:$ 45.2
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Chem-Impex
  • Product Description:Sodiummethoxide,25wt.%inmethanol,24.4%-25.5%byWeightofSodiummethoxideinMethanol 24.4%-25.5%byWeightofSodiummethoxideinMethanol
  • Packaging:1L
  • Price:$ 100.8
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Chem-Impex
  • Product Description:Sodiummethoxide,0.5MMethanolicSolution,0.48-0.52molesodiummethoxideperlitersolution(25.9-28.1g/L)(Titration),ACSreagentHazmat 0.48-0.52molesodiummethoxideperlitersolution(25.9-28.1g/L)(Titration)
  • Packaging:100ML
  • Price:$ 104.83
  • Delivery:In stock
  • Buy Now

Relevant articles and documentsAll total 109 Articles be found

Broensted Acidities of Carbonyl Hydride Complexes of Iron, Ruthenium, and Osmium: pKa Values and Deprotonation Rates in Methanol Solution

Walker, Howard W.,Pearson, Ralph G.,Ford, Peter C.

, p. 1179 - 1186 (1983)

Reported are kinetics studies of the reaction of methoxide ion with several mononuclear and polynuclear carbonyl hydride complexes HxMy(CO)z of the iron triad.Deprotonation of the hydrides to give the conjugate base anions occurs with moderate second-order rate constants (ca. 101-104 M-1s-1), considerably smaller than those of oxygen or nitrogen acids of comparable thermodynamic strength under similar conditions.The relative slowness of these reactions is interpreted in terms of possible electronic and structural rearrangements of substrate and solvent occuring as the result of the deprotonation.In addition the kinetics technique allows the measurement of the reverse reacton (protonation of the conjugate base by methanol) rate constants which are also comparatively small (ca. 0.05-25 s-1).The ratio of the forward and reverse rates gives the equilibrium constants from which the pKa's in methanol can be calculated.In several cases pKa's were confirmed by buffer/indicator techniques.From these and other published data are drawn the conclusions that bridging hydrides are more acidic than terminal hydrides and that hydrides of the lighter metals are more acidic than those of homologous heavier metals.Furthermore, it is shown than the substituent effect of replacing CO of a cluster by a trimethyl phosphite is to decrease significantly the acidity of that cluster's hydrides.

-

Fendler,E.J. et al.

, p. 812 - 819 (1972)

-

Kinetic Studies on the Decomposition of Most Typical Meisenheimer Complex of Sodium 1,1-Dimethoxy-2,4,6-trinitrocyclohexadienide in Methanol

Abe, Takehiro

, p. 1399 - 1405 (1980)

The whole decomposition of the Meisenheimer complex formed from 2,4,6-trinitroanisole (TNA) and sodium methoxide proceeds in three steps and obeys the first-order kinetics in each step.The rate of the whole decrease of concentration of the complex is given by -d(+->)/dt=(k1+>+k2)*+(k3+>+k4)*->-k5->*, where k denotes a rate constant.This leads to the modification of the conventional unimolecular mehanism shown by TNA*CH3O- -> TNA +CH3O-.

Identification of 1, 4-Dihydrothieno[3', 2':5, 6]thiopyrano [4, 3-c]pyrazole derivatives as human 5-lipooxygenase inhibitors

Hu, Jianshu,Zhu, Wei,Meng, Hu,Liu, Ying,Wang, Xin,Hu, Chun

, p. 642 - 647 (2014)

A series of novel 1,4-dihydrothieno[3',2':5,6]thiopyrano [4,3-c]-pyrazole-3-carboxamide derivatives were synthesized and evaluated for their inhibitory activity to human 5-lipo-oxygenase (5-LOX). Compound 7c was found to exhibit significant inhibition to human 5-LOX with IC50 value of 5.7 ± 0.9 μM. Compound 7c was further studied using molecular docking in order to delineate its structure-activity relationship and to gain insight into the design of effective 5-LOX inhibitors.

Standard molar enthalpies of formation of sodium alkoxides

Chandran,Srinivasan,Gopalan,Ganesan

, p. 449 - 454 (2007)

The molar enthalpies of solution of sodium in methanol, ethanol, and n-propanol and of sodium alkoxides in their corresponding alcohols were measured at T = 298.15 K using an isoperibol solution calorimeter. From these results and other auxiliary data, the standard molar enthalpies of formation Δf Hm{ring operator} (RONa,cr) of sodium methoxide, sodium ethoxide, and sodium n-propoxide were calculated and found to be {(-366.21 ± 1.38), (-413.39 ± 1.45), and (-441.57 ± 1.18)} kJ · mol-1, respectively. A linear correlation has been found between Δf Hm{ring operator} (RONa) and Δf Hm{ring operator} (ROH) for R = n-alkyl, enabling the prediction of data for other sodium alkoxides.

Synthesis and antimicrobial activities evaluation of some new thiadiazinone and thiadiazepinone derivatives bearing sulfonamide moiety

Dalloul, Hany M. M.,El-Nwairy, Khaled A.,Shorafa, Ali Z.,Abu Samaha, Ahmed S.

, p. 288 - 293 (2018)

A new series of novel functionalized 1,3,4-thiadiazin-5-ones and 1,3,4-thiadi-azepin-5-ones bearing sulfonamide moieties were synthesized via 1,3-dipolar cyclocondensation reaction of nitrilimines with α-mercaptoesters and mercaptosuccinic acid respectively. The structures of the prepared compounds were confirmed by spectral methods (IR, 1H-NMR, 13C-NMR and MS spectroscopy) and elemental analysis. The newly synthesized compounds were screened for their in vitro antimicrobial activity. Some of titled compounds exhibited significant antimicrobial activity on several strains of microbes.

Synthesis and evaluation of the cytotoxic activity of water-soluble cationic organometallic complexes of the type [Pt(η1-C2H4OMe)(L)(phen)]+ (L = NH3, DMSO; phen = 1,10-phenanthroline)

De Castro, Federica,Stefàno, Erika,Migoni, Danilo,Iaconisi, Giorgia N.,Muscella, Antonella,Marsigliante, Santo,Benedetti, Michele,Fanizzi, Francesco P.

, (2021)

Starting from the [PtCl(η1-C2H4OMe)(phen)] (phen = 1,10-phenanthroline, 1) platinum(II) precursor, we synthesized and characterized by multinuclear NMR new [Pt(η1-C2H4OMe)(L)(phen)]+ (L = NH3, 2; DMSO, 3) complexes. These organometallic species, potentially able to interact with cell membrane organic cation transporters (OCT), violating some of the classical rules for antitumor activity of cisplatin analogues, were evaluated for their cytotoxicity. Interestingly, despite both complexes 2 and 3 resulting in greater cell uptake than cisplatin in selected tumor cell lines, only 3 showed comparable or higher antitumor activity. General low cytotoxicity of complex 2 in the tested cell lines (SH-SY5Y, SK-OV-3, Hep-G2, Caco-2, HeLa, MCF-7, MG-63, ZL-65) appeared to depend on its stability towards solvolysis in neutral water, as assessed by NMR monitoring. Differently, the [Pt(η1-C2H4OMe)(DMSO)(phen)]+ (3) complex was easily hydrolyzed in neutral water, resulting in a comparable or higher cytotoxicity in cancer cells with respect to cisplatin. Further, both IC50 values and the uptake profiles of the active complex appeared quite different in the used cell lines, suggesting the occurrence of diversified biological effects. Nevertheless, further studies on the metabolism of complex 3 should be performed before planning its possible use in tissue- and tumor-specific drug design.

Anti-Helicobacter pylori activity of some newly synthesized derivatives of xanthone

Klesiewicz, Karolina,Karczewska, Elzbieta,Budak, Alicja,Marona, Henryk,Szkaradek, Natalia

, p. 825 - 834 (2016)

A series of 20 xanthone derivatives was synthesized and evaluated for anti-Helicobacter pylori (H. pylori) activity. Qualitative and quantitative in vitro tests using the Kirby-Bauer method (agar disc-diffusion method) were performed. The tested compounds were screened against clarithromycin- and/or metronidazole-resistant strains of H. pylori. As a reference, Gram-positive (Staphylococcus aureus) and Gram-negative (Escherichia coli) bacterial strains were examined. On the basis of microbiological assays, xanthones can be considered as potential anti-H. pylori agents. They displayed significant activity against the examined strains, which was higher against the bacteria resistant to metronidazole than clarithromycin. The lowest MIC values ranging up to 20 mg l-1 were observed for the following compounds: 3, 4, 8, 9, 12, 19 (against the metronidazole-resistant strains) and the compound 10 (against the clarithromycin-resistant strain). These preliminary results for screening of xanthone derivatives form a part of an ongoing study of the structure-activity relationships of a large group of compounds. Microbiological assays will be conducted afterwards to determine the mechanism of xanthones' action against H. pylori.

Investigation of the crystal structures and magnetic features of two bis(dithiolato)nickelate salts with flexible organic cations

Chen, Xuan-Rong,Zhang, Zhen-Min,Luo, Min,Liu, Hang,Yuan, Jia-Yi

, p. 353 - 362 (2021)

Two bis(dithiolato)nickel salts with different flexible ammonium counterions, [Et3MeN][Ni(dmit)2] (1) and [(i-Bu)Et3N][Ni(dmit)2] (2) (dmit2? = 2-thioxo-1,3-dithiole-4,5-dithiolate, Et3MeN+ = triethylmethylammonium, (i-Bu)Et3N+ = triethylisobutylammonium), are prepared and identified by powder X-ray diffraction (PXRD) patterns and single-crystal X-ray diffraction. Salt 1 crystallizes in the triclinic space group P???1 at 293?K. The anions and cations in 1 form alternating layered arrangements along the a-axis direction. Salt 2 belongs to the monoclinic crystal system and space group P21/n. The anions and cations in 2 form separate columnar stacks along bc-plane direction. The neighboring anions are stacked as dimers in the anion columnar stacks of 2. The magnetic features of salts 1 and 2 show 1D alternating spin chain magnetic exchange behavior, and the magnetic experimental data are well fitted through a spin chain magnetic model. The difference in the crystal structures and magnetic properties between the two new salts 1 and 2 fully demonstrates that the magnetic properties are dependent on the alignment of the [Ni(dmit)2]? anions, which are related to the flexible organic cations. Graphical abstract: [Figure not available: see fulltext.]

Near-infrared light-controlled circularly polarized luminescence of self-organized emissive helical superstructures assisted by upconversion nanoparticles

Juan, Ao,Sun, Hao,Qiao, Jinghui,Guo, Jinbao

, p. 13649 - 13652 (2020)

A near-infrared light-driven self-organized emissive helical superstructure was constructed by doping a new chiral fluorescent photoswitch and upconversion nanoparticles (UCNPs) into a nematic LC. The reversible switching of circularly polarized luminescence (CPL) can be achieved by modulating the power intensity of the 980 nm NIR excitation light.

-

Crampton,M.R. et al.

, p. 825 - 826 (1975)

-

Synthesis and herbicidal activities of novel 3-(α-hydroxymethylene) pyrrolidine-2,4-dione derivatives containing a cyclopropane moiety

Zhu, You-Quan,Zhang, Jin,Yuan, Yan-Wei,Xie, Li-Fen,Xu, Hai-Zhen,Zou, Xiao-Mao,Yang, Hua-Zheng

, p. 202 - 205 (2013)

A variety of novel 3-(α-hydroxymethylene)pyrrolidine-2,4-dione derivatives containing a cyclopropane moiety were designed and synthesized in satisfactory yields. Their structures were confirmed by 1H NMR and HRMS. The bioassays indicated that most of the title compounds displayed some extent herbicidal activities at 100 mg/mL.

Chemical transformations and biological studies of terpenoids isolated from essential oil of Cyperus scariosus

Sharma,Utreja,Bedi

, p. 2153 - 2158 (2016)

Cyperus scariosus is a potential medicinal herb belonging to the family Cyperaceae. The GC-MS analysis of the oil showed cyprene (18.57 %) as the major terpene present in it. Cyprene was isolated from the non-polar fraction of the oil using hexane as solvent and characterized using TLC and spectral techniques (IR and 1H NMR). Cyprene was derivatized to cyprene epoxide by two methods i.e. using perbenzoic acid and epichlorohydrin. Further, the oil, it's polar fraction (dichloromethane), non-polar fraction (hexane), cyprene and cyprene epoxide were screened for their plant growth regulating property in case of wheat seedlings (HD 2967 and PBW 621). Complete germination was observed above 2.5 μg/mL of all the test fractions in both the cultivars. Moreover, cyprene epoxide was found to be the most effective in enhancing the length of roots and shoots. Seedling vigour index was calculated in order to analyze the enhancement shown by the oil and its various components on the seedlings.

Synthesis and structure of hypercoordinated germanate complexes with naphthalene-2,3-dialkoxide ligands

Goto, Mitsuki,Nakashima, Yuta,Nanjo, Masato

, (2021)

The synthesis of six-coordinated germanate complexes with naphthalene-2,3-dialkoxide ligands with alkali metals (Li, Na, and K) as counter ions are described. The molecular structures of lithium and potassium germanate complexes were clarified by X-ray diffraction analysis. Each germanium center atom is coordinated by six oxygen atoms to form slightly distorted octahedral configuration. All the compounds were thermally stable up to 300 °C determined by thermogravimetric analysis under air-flow conditions.

Synthesis, monoamine oxidase inhibition activity and molecular docking studies of novel 4-hydroxy-N′-[benzylidene or 1-phenylethylidene]-2-H/methyl/benzyl-1,2-benzothiazine-3-carbohydrazide 1,1-dioxides

Saddique, Furqan Ahmad,Zaib, Sumera,Jalil, Saquib,Aslam, Sana,Ahmad, Matloob,Sultan, Sadia,Naz, Humera,Iqbal, Mazhar,Iqbal, Jamshed

, p. 1373 - 1386 (2018)

Three series of 4-hydroxy-N′-[benzylidene/1-phenylethylidene]-2-H/methyl/benzyl-1,2-benzothiazine-3-carbohydrazide 1,1-dioxides (9–11)a-l were synthesized and unraveled to be highly potent dual inhibitors of monoamine oxidases (MAO-A and MAO-B). All the examined compounds demonstrated IC50 values in lower micro-molar range for both MAO-A as well as MAO-B. The most active MAO-A inhibitor was 4-hydroxy-N′-(1-phenylethylidene)-2H-benzo[e][1,2]thiazine-3-carbohydrazide 1,1-dioxide (9i) with an IC50 value of 0.11 ± 0.005 μM, whereas, methyl 4-hydroxy-2H-benzo[e][1,2]thiazine-3-carboxylate 1,1-dioxide (3) was the most active MAO-B inhibitor with an IC50 value of 0.21 ± 0.01 μM. Enzyme kinetics studies revealed that the most potent compounds inhibited both MAO enzymes (A & B) in a competitive fashion. Molecular docking studies were also performed to obtain an intuitive picture of inhibition potential for potent inhibitors. The high potency of these compounds is optimally combined with highly favorable ADME profile with predicted good oral bioavailability.

Evolution of the Synthesis of AMPK Activators for the Treatment of Diabetic Nephropathy: From Three Preclinical Candidates to the Investigational New Drug PF-06409577

Smith, Aaron C.,Kung, Daniel W.,Shavnya, Andre,Brandt, Thomas A.,Dent, Philip D.,Genung, Nathan E.,Cabral, Shawn,Panteleev, Jane,Herr, Michael,Yip, Ka Ning,Aspnes, Gary E.,Conn, Edward L.,Dowling, Matthew S.,Edmonds, David J.,Edmonds, Ian D.,Fernando, Dilinie P.,Herrinton, Paul M.,Keene, Nandell F.,Lavergne, Sophie Y.,Li, Qifang,Polivkova, Jana,Rose, Colin R.,Thuma, Benjamin A.,Vetelino, Michael G.,Wang, Guoqiang,Weaver, John D.,Widlicka, Daniel W.,Price Wiglesworth, Kristin E.,Xiao, Jun,Zahn, Todd,Zhang, Yingxin

, p. 681 - 696 (2018)

Indole acids 1, 2, and 3 are potent 5′-adenosine monophosphate-activated protein kinase (AMPK) activators for the potential treatment of diabetic nephropathy. Compounds 1-3 were scaled to supply material for preclinical studies, and indole 3 was selected for advancement to first-in-human clinical trials and scaled to kilogram quantities. The progression of the synthesis strategy for these AMPK activators is described, as routes were selected for efficient structure-activity relationship generation and then improved for larger scales. The developed sequences employed practical isolations of intermediates and APIs, reproducible cross-coupling, hydrolysis, and other transformations, and enhanced safety and purity profiles and led to the production of 40-50 g of 1 and 2 and 2.4 kg of 3. Multiple polymorphs of 3 were observed, and conditions for the reproducible formation of crystalline material suitable for clinical development were identified.

Ni-Catalyzed 1,2-Diarylation of Alkenyl Ketones: A Comparative Study of Carbonyl-Directed Reaction Systems

Apolinar, Omar,Derosa, Joseph,Engle, Keary M.,Karunananda, Malkanthi K.,Kleinmans, Roman,Li, Zi-Qi,Tran, Van T.,Wisniewski, Steven R.

supporting information, p. 5311 - 5316 (2021/07/26)

A nickel-catalyzed 1,2-diarylation of alkenyl ketones with aryl iodides and arylboronic esters is reported. Ketones with a variety of substituents serve as effective directing groups, offering high levels of regiocontrol. A representative product is diversified into a wide range of useful products that are not readily accessible via existing 1,2-diarylation reactions. Preliminary mechanistic studies shed light on the binding mode of the substrate, and Hammett analysis reveals the effect of electronic factors on initial rates.

Bithiazole Inhibitors of Phosphatidylinositol 4-Kinase (PI4KIIIβ) as Broad-Spectrum Antivirals Blocking the Replication of SARS-CoV-2, Zika Virus, and Human Rhinoviruses

Grazia Martina, Maria,Vicenti, Ilaria,Bauer, Lisa,Crespan, Emmanuele,Rango, Enrico,Boccuto, Adele,Olivieri, Noemi,Incerti, Matteo,Zwaagstra, Marleen,Allodi, Marika,Bertoni, Simona,Dreassi, Elena,Zazzi, Maurizio,van Kuppeveld, Frank J. M.,Maga, Giovanni,Radi, Marco

supporting information, p. 3548 - 3552 (2021/09/09)

Over half a century since the description of the first antiviral drug, “old” re-emerging viruses and “new” emerging viruses still represent a serious threat to global health. Their high mutation rate and rapid selection of resistance toward common antiviral drugs, together with the increasing number of co-infections, make the war against viruses quite challenging. Herein we report a host-targeted approach, based on the inhibition of the lipid kinase PI4KIIIβ, as a promising strategy for inhibiting the replication of multiple viruses hijacking this protein. We show that bithiazole inhibitors of PI4KIIIβ block the replication of human rhinoviruses (hRV), Zika virus (ZIKV) and SARS-CoV-2 at low micromolar and sub-micromolar concentrations. However, while the anti-hRV/ZIKV activity can be directly linked to PI4KIIIβ inhibition, the role of PI4KIIIβ in SARS-CoV-2 entry/replication is debated.

Process route upstream and downstream products

Process route

Trimethylmethoxysilane
1825-61-2

Trimethylmethoxysilane

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

sodium methylate
124-41-4

sodium methylate

sodium trimethylsilanolate
18027-10-6

sodium trimethylsilanolate

Conditions
Conditions Yield
With sodium hydroxide; at 0 - 35 ℃; for 0.05h;
10.0 g
Natrium-1-cyan-2-methoxy-3.5-dinitro-2H-cyclohexadienylid

Natrium-1-cyan-2-methoxy-3.5-dinitro-2H-cyclohexadienylid

3,5-dinitrobenzonitrile
4110-35-4

3,5-dinitrobenzonitrile

sodium methylate
124-41-4

sodium methylate

Conditions
Conditions Yield
In methanol; dimethyl sulfoxide; at 25 ℃; Equilibrium constant;
methanol
67-56-1

methanol

p-nitro-phenyl-acetonitrile
48129-94-8

p-nitro-phenyl-acetonitrile

sodium methylate
124-41-4

sodium methylate

4-Nitrophenylacetonitrile
555-21-5,34512-13-5,174848-08-9

4-Nitrophenylacetonitrile

Conditions
Conditions Yield
at 25 ℃; Equilibrium constant;
methanol
67-56-1

methanol

2-cyanobenzyl cyanide anion
163977-20-6

2-cyanobenzyl cyanide anion

(2-cyanophenyl)acetonitrile
3759-28-2

(2-cyanophenyl)acetonitrile

sodium methylate
124-41-4

sodium methylate

Conditions
Conditions Yield
at 25 ℃; Equilibrium constant;
1,2-dibromo-3-methoxypropane
5836-66-8

1,2-dibromo-3-methoxypropane

sodium amide

sodium amide

sodium methylate
124-41-4

sodium methylate

propargyl alcohol methyl ether
627-41-8

propargyl alcohol methyl ether

Conditions
Conditions Yield
methanol
67-56-1

methanol

ethyl cyanoacetate anion
31124-95-5

ethyl cyanoacetate anion

sodium methylate
124-41-4

sodium methylate

ethyl 2-cyanoacetate
105-56-6

ethyl 2-cyanoacetate

Conditions
Conditions Yield
at 25 ℃; Equilibrium constant;
methanol
67-56-1

methanol

bis-methoxycarbonyl-methanide
33673-07-3

bis-methoxycarbonyl-methanide

sodium methylate
124-41-4

sodium methylate

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

Conditions
Conditions Yield
at 25 ℃; Equilibrium constant;
C<sub>8</sub>H<sub>8</sub>N<sub>3</sub>O<sub>7</sub><sup>(1-)</sup>*Na<sup>(1+)</sup>

C8H8N3O7(1-)*Na(1+)

2,4,6-Trinitrotoluene
118-96-7

2,4,6-Trinitrotoluene

sodium methylate
124-41-4

sodium methylate

Conditions
Conditions Yield
In methanol; dimethyl sulfoxide; at 25 ℃; Rate constant; Equilibrium constant;
sodium trimethoxyborohydride

sodium trimethoxyborohydride

sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

Trimethyl borate
121-43-7,63156-11-6

Trimethyl borate

sodium methylate
124-41-4

sodium methylate

Conditions
Conditions Yield
byproducts: (CH3)2BH; equilibrium reaction, 230°C, disproportionation;
byproducts: (CH3)2BH; equilibrium reaction, 230°C, disproportionation;
byproducts: (CH3)2BH; equilibrium reaction, 230°C, disproportionation;
sodium tetramethoxyborate
18024-69-6

sodium tetramethoxyborate

Trimethyl borate
121-43-7,63156-11-6

Trimethyl borate

sodium methylate
124-41-4

sodium methylate

Conditions
Conditions Yield
at 210 - 240 ℃; im Vakuum;
210-280°C;
210-280°C;
210-280°C;

Global suppliers and manufacturers

Global( 76) Suppliers
  • Company Name
  • Business Type
  • Contact Tel
  • Emails
  • Main Products
  • Country
  • Hangzhou Dingyan Chem Co., Ltd
  • Business Type:Manufacturers
  • Contact Tel:86-571-86465881,86-571-87157530,86-571-88025800
  • Emails:sales@dingyanchem.com
  • Main Products:95
  • Country:China (Mainland)
  • EAST CHEMSOURCES LIMITED
  • Business Type:Manufacturers
  • Contact Tel:86-532-81906761
  • Emails:josen@eastchem-cn.com
  • Main Products:97
  • Country:China (Mainland)
  • Amadis Chemical Co., Ltd.
  • Business Type:Lab/Research institutions
  • Contact Tel:86-571-89925085
  • Emails:sales@amadischem.com
  • Main Products:29
  • Country:China (Mainland)
  • COLORCOM LTD.
  • Business Type:Manufacturers
  • Contact Tel:+86-571-89007001
  • Emails:medkem@medkem.cn
  • Main Products:1
  • Country:China (Mainland)
  • Shanghai Upbio Tech Co.,Ltd
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-21-52196435
  • Emails:upbiocn@hotmail.com
  • Main Products:88
  • Country:China (Mainland)
close
Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 124-41-4
Post Buying Request Now
close
Remarks: The blank with*must be completed