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Cas Database

127-09-3

127-09-3

Identification

  • Product Name:Sodium acetate

  • CAS Number: 127-09-3

  • EINECS:204-823-8

  • Molecular Weight:82.0344

  • Molecular Formula: C2H3NaO2

  • HS Code:29152200

  • Mol File:127-09-3.mol

Synonyms:Natriumazetat;Acetic acid,compounds,sodium salt;Natriumacetat;Acetic acid, sodium salt;Anhydrous sodium acetate;Anhydrous sodium acetate(Technical grade);Sodium acetate ANH;Anhydrous sodium acetate ( Pharmaceutical grade);Anhydrous sodium acetate ( Food grade);Industrial Sodium Acetate Anhydrous;

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Safety information and MSDS view more

  • Signal Word:No signal word.

  • Hazard Statement:none

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

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  • Manufacture/Brand:Usbiological
  • Product Description:Sodium Acetate Anhydrous, ACS
  • Packaging:500g
  • Price:$ 50
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  • Manufacture/Brand:TRC
  • Product Description:Sodium acetate
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  • Manufacture/Brand:Tocris
  • Product Description:Sodium acetate ≥99%
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  • Manufacture/Brand:Strem Chemicals
  • Product Description:Sodium acetate, anhydrous, 99+% (ACS)
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  • Manufacture/Brand:Strem Chemicals
  • Product Description:Sodium acetate, anhydrous, 99+% (ACS)
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Sodium acetate anhydrous for analysis EMSURE ACS,Reag. Ph Eur
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Sodium acetate anhydrous for analysis EMSURE? ACS,Reag. Ph Eur
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Sodium acetate anhydrous 99.99 Suprapur . CAS No. 127-09-3, EC Number 204-823-8., anhydrous 99.99 Suprapur
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Sodium acetate ACS reagent, ≥99.0%
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Sodium acetate puriss. p.a., ACS reagent, reag. Ph. Eur., anhydrous
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Relevant articles and documentsAll total 55 Articles be found

Depree,Closson

, p. 2311 (1958)

Synthesis and characterization of copper(II), iron(II), cobalt(II), nickel(II) and manganese(II) complexes of azido-1,4-bis(imidazol-1-YL-methyl)benzene (bix) or 1,4-bis(imidazol-1-YL-methyl)-2,5-dimethyl-benzene) (Mebix)

Shen, Hao-Yu,Liao, Dai-Zheng,Jiang, Zong-Hui,Yan, Shi-Ping,Wang, Geng-Lin

, p. 1331 - 1338 (1999)

Cu(II), Fe(II), Co(II), Ni(II), Mn(II) complexes of azido-1,4-bis(imidazol-1-yl-methyl)benzene (bix) or 1,4-bis(imidazol-1-yl-methyl)-2,5-dimethyl-benzene) (Mebix) were synthesized by the spontaneous self-assembly method. The compounds [Cu2(bix

A new, more efficient procedure for the preparation of potassium tris(malonto)cobaltate(III) dihydrate

Miodragovic, Zoran M.,Vuckovic, Gordana

, p. 1451 - 1461 (1999)

A new, very efficient and elegant procedure for the preparation of potassium tris(malonato)cobaltate(III) dihydrate, starting from Co(OH)3 and potassium hydrogenmalonate, is presented. The most important advantages of this procedure, in comparison to the previously reported ones, are: a relatively short time required, saving of the reagents and solvents, and a very good yield of pure product. The identification of the obtained complex was carried out by elemental analyses, electronic absorption and IR spectroscopy. The spectral data are in accordance with the previously reported literature data. Analogous procedure was also preliminary tested for the preparation of the corresponding tris(oxalato)-and tris(succinato)cobaltate(III). Finally, the described complex can be used as a starting material for the preparation of one mixed ligand Co(III) complex.

A polyoxometalate-assisted approach for synthesis of Pd nanoparticles on graphene nanosheets: Synergistic behaviour for enhanced electrocatalytic activity

Khadempir, Sara,Ahmadpour, Ali,Hamed Mosavian, Mohammad T.,Ashraf, Narges,Bamoharram, Fatemeh F.,Mitchell, Scott G.,De La Fuente, Jesús M.

, p. 24319 - 24326 (2015)

A polyoxometalate (POM) assisted approach has been employed to prepare a nanohybrid of Pd nanoparticles (PdNPs) and graphene nanosheets (GNSs). The Keggin-type POM, phosphomolybdic acid (PMo12), was applied to serve as both reducing and stabilising agent. The as-prepared nanohybrid (Pd/PMo12/GNSs) was comprehensively characterised using transmission electron microscopy and X-ray diffraction analysis. The synergistic behaviour of PdNPs, PMo12 and GNSs in the nanohybrid leads to elevated electrocatalytic property for ethanol oxidation. Moreover, the Pd/PMo12/GNSs nanohybrid was activated by applying a sufficiently negative potential which plays a key role in promoting the electrocatalytic activity. The activated catalyst presents a superior performance towards ethanol electrooxidation reaction and shows better tolerance to poisoning species compared to Pd and Pt nanoparticles. The outstanding electrocatalytic activity of the tri-component (Pd/PMo12/GNSs) nanohybrid is discussed with relevance to its application in direct alcohol fuel cells (DAFCs).

Efficient Iridium Catalysts for Formic Acid Dehydrogenation: Investigating the Electronic Effect on the Elementary β-Hydride Elimination and Hydrogen Formation Steps

Liu, Hong,Wang, Wan-Hui,Xiong, Huatian,Nijamudheen,Ertem, Mehmed Z.,Wang, Mei,Duan, Lele

, p. 3410 - 3417 (2021)

We report herein a series of Cp*Ir complexes containing a rigid 8-aminoquinolinesulfonamide moiety as highly efficient catalysts for the dehydrogenation of formic acid (FA). The complex [Cp*Ir(L)Cl] (HL = N-(quinolin-8-yl)benzenesulfonamide) displayed a high turnover frequency (TOF) of 2.97 × 104 h-1 and a good stability (>100 h) at 60 °C. Comparative studies of [Cp*Ir(L)Cl] with the rigid ligand and [Cp*Ir(L′)Cl] (HL′ = N-propylpypridine-2-sulfonamide) without the rigid aminoquinoline moiety demonstrated that the 8-aminoquinoline moiety could dramatically enhance the stability of the catalyst. The electron-donating ability of the N,N′-chelating ligand was tuned by functionalizing the phenyl group of the L ligand with OMe, Cl, and CF3 to have a systematical perturbation of the electronic structure of [Cp*Ir(L)Cl]. Experimental kinetic studies and density functional theory (DFT) calculations on this series of Cp*Ir complexes revealed that (i) the electron-donating groups enhance the hydrogen formation step while slowing down the β-hydride elimination and (ii) the electron-withdrawing groups display the opposite effect on these reaction steps, which in turn leads to lower optimum pH for catalytic activity compared to the electron-donating groups.

Sharma, S. K.,Jotshi, C. K.,Kumar, Suniti

, p. 9 - 24 (1991)

Synthesis and characterization of complexes of some hydroxyaryltellurium trichlorides with N-donor ligands

Verma,Dahiya, Reena,Soni, Daya

, p. 1033 - 1052 (1999)

Twenty new complexes of hydroxyaryltellurium trichlorides derived from isomeric cresols and ortho-chlorophenol with pyridine (Py), 2,2′-bipyridyl (Bipy) and piperidine (Pip) have been synthesized and characterized by elemental analyses, conductance, cryoscopy, infrared and proton magnetic resonance studies. Pyridine and piperidine form RTeCl3.L and RTeCl3.2L complexes, whereas 2,2′-bipyridyl which acts as a bidentate ligand and gives only RTeCl3.L complexes. Conductance and cryoscopic measurements reflect their weak or 1:1 electrolytic behaviour in solution of nitrobenzene, acetonitrile and acetone. Spectral studies indicate the linkage of these ligand molecules to the tellurium atom of the hydroxyaryltellurium group through nitrogen atoms. A square-pyramidal structure is suggested for RTeCl3.Py and RTeCl3.Pip, whereas 1:2 complexes of pyridine and piperidine along with RTeCl3.Bipy, have octahedral stereochemistry.

The selective oxidation of 1,2-propanediol to lactic acid using mild conditions and gold-based nanoparticulate catalysts

Ryabenkova, Yulia,He, Qian,Miedziak, Peter J.,Dummer, Nicholas F.,Taylor, Stuart H.,Carley, Albert F.,Morgan, David J.,Dimitratos, Nikolaos,Willock, David J.,Bethell, Donald,Knight, David W.,Chadwick, David,Kiely, Christopher J.,Hutchings, Graham J.

, p. 139 - 145 (2013)

The use of bio-renewable resources for the generation of materials and chemicals continues to attract significant research attention. It is well established that glycerol is an excellent starting material for the production of 1,2-propanediol by dehydration/hydrogenation and that this can subsequently be oxidised to lactic acid, which has the potential to be used as a major chemical in the production of biodegradable polymers. Previous studies using gold catalysts for the oxidation of 1,2-propanediol have used elevated temperatures and pressures. We now show that the oxidation of 1,2-propanediol to form lactic acid can be carried out selectively under mild reaction conditions with gold-platinum catalysts prepared using a sol-immobilisation method, with activated carbon as the support. Carrying out the reaction at ambient temperature with air significantly improves the reaction in terms of its environmental impact and its industrial attractiveness, as lactic acid can be obtained with high selectivity.

Interaction of cobalt(II) and copper(II) with polyoxometallates. Structure of Na3Co[IMo6O24]. 14H2O

Rosu, Cristina,Gomez-Garcia, Carlos Jose,Dickman, Michael H.,Rusu, Mariana

, p. 1123 - 1131 (1999)

Cobalt(II) and copper(II) complexes with the ligand anion [IMo6O24]5- (periodate 6-molybdoanion) of the general formula Na3M[IMo6O24].nH2O (where M = Co, Cu) have been prepared by the reaction of the corresponding metal salts with the ligand in aqueous media (pH = 6). The complexes were characterised by elemental and thermogravimetric analyses, spectral data (IR, UV-vis). The EPR spectrum of a copper(II) powder sample was recorded at both room temperature and 12 K indicating a weakly distorted octahedral copper(II) stereochemistry. The crystal structure of Na3CO[IMo6O24]. 14H2O has been determined by single-crystal X-ray diffraction technique.

Fluorescent monitoring of the reaction kinetics of nonfluorescent molecules enabled by a fluorescent receptor

Bai, Lin-Ming,Zhou, Hang,Liu, Wei-Er,Chai, Hongxin,Yang, Liu-Pan,Yan, Wei,Zhang, Wen,Yang, Hong-Hui,Jiang, Wei

, p. 3128 - 3131 (2019)

A facile fluorescent method was developed to quantitatively monitor the hydrolysis kinetics of nonfluorescent esters by using a fluorecent endo-functionalized molecular tube and its recognition ability towards small polar molecules in water. It is possible to determine the apparent rate constants and study the structure-activity relationship.

Seyb, E.,Kleinberg, J.

, p. 115 - 117 (1951)

In situ FTIR spectroscopic studies of electrooxidation of ethanol on Pd electrode in alkaline media

Zhou, Zhi-You,Wang, Qiang,Lin, Jian-Long,Tian, Na,Sun, Shi-Gang

, p. 7995 - 7999 (2010)

Electrooxidation of ethanol on a polycrystalline Pd disk electrode in alkaline media was studied by in situ Fourier transform infrared (FTIR) reflection spectroscopy. The emphasis was put on the quantitative determination of intermediates and products involved in the oxidation. It has revealed that most of ethanol was incompletely oxidized to acetate. The selectivity for ethanol oxidation to CO2 (existing as CO32- in alkaline media) was determined as low as 2.5% in the potential region where Pd electrode exhibited considerable electrocatalytic activity (-0.60 to 0.0 V vs. SCE). Nevertheless, the ability of Pd for breaking C-C bond in ethanol is still slightly better than that of Pt under the same conditions. Besides, a very weak band of adsorbed intermediate, bridge-bonded CO (COB) was identified on the Pd electrode for the first time, suggesting that CO2 and CO32- species may also be generated through CO pathway (i.e., indirect pathway).

Selective formation of lactate by oxidation of 1,2-propanediol using gold palladium alloy supported nanocrystals

Dimitratos, Nikolaos,Lopez-Sanchez, Jose Antonio,Meenakshisundaram, Sankar,Anthonykutty, Jinto Manjaly,Brett, Gemma,Carley, Albert F.,Taylor, Stuart H.,Knight, David W.,Hutchings, Graham J.

, p. 1209 - 1216 (2009)

The use of bio-renewable resources, such as glycerol, a by-product from bio-diesel manufacture, can provide a viable way to make valuable products using greener technology. In particular, glycerol can be reduced to give 1,2-propanediol that can then be se

Altering the polymorphic product distribution in a solid-state dehydration process by rapid sample rotation in a solid-state NMR probe

Xu, Mingcan,Harris, Kenneth D. M.

, p. 10832 - 10833 (2005)

-

Carrol

, p. 143 (1918)

-

Reid,Worthington,Larchar

, p. 100 (1939)

-

Beck

, p. 155 (1937)

The Stereoselective Retardation of the Alkaline Hydrolysis of Organic Esters by Binuclear Cu(II) Complexes with Cyclodextrins

Matsui, Yoshihisa,Suemitsu, Daisuke

, p. 1658 - 1662 (1985)

The alkaline hydrolysis of p-nitrophenyl acetate (p-NPA) in 1.0 mol dm-3 NaOH at 25 deg C was almost completely retarded by the addition of a binuclear Cu(II) complex with α-cyclodextrin Cu2α-CD).The dissociation constant for an inclusion complex of Cu2α-CD with p-NPA was determined to be 0.059 mmol dm-3, which is about one 200th that for an inclusion complex of α-CD with p-NPA.The alkaline hydrolysis of o- and m-nitrophenyl acetates was also retarded by Cu2α-CD, though the extent of retardation was much less than that for p-NPA.A binuclear Cu(II) complex with β-cyclodextrin (Cu2β-CD) also caused a stereoselective deceleration of the alkaline hydrolysis of the esters.However, the stereoselectivity of Cu2β-CD was not so remarkable as that of Cu2α-CD.Dissociation constants for inclusion complexes of Cu2α-CD with several alcohols and other organic substrates were determined by the kinetic examination of the competitive inhibition effect of the substrates on the association of Cu2α-CD with p-NPA.Cu2α-CD formed stable inclusion complexes with such disk-like molecules as cyclohexanol, cycloheptanol, and p-nitrobenzyl alcohol.The geometry of a Cu2α-CD-p-NPA inclusion complex was presumed on the basis of these results.

No contribution of an inductive effect to secondary deuterium isotope effects on acidity

Perrin, Charles L.,Flach, Agnes

, p. 7674 - 7676 (2011)

Effect and cause: Secondary deuterium isotope effects on the acidity of the deuterated compounds 1-4 were measured by using an NMR titration method applicable to a mixture and capable of very high accuracy. Variable-temperature experiments show that these isotope effects are due only to changes in vibrational frequencies. These findings refute an inductive origin for these isotope effects. Copyright

Synthesis of a Novel Tri-enaminone as Building Block for Polyaza-heterocycles

Farghaly, Thoraya A.,Abdallah, Magda A.,Abdel Aziz, Mohamed R.

, p. 699 - 705 (2017)

The new tri-enaminone, namely, 3,4-bis(3-dimethylamino-2-propenoyl)-1-[4-(3-dimethylamino-2-propenoyl)phenyl]-5-methyl-1H-pyrazole was prepared and used as building block for synthesis of novel polyaza-heterocycles. The latter compounds were obtained via an efficient one-pot reaction of the tri-enaminone with 1,3-dipoles and various electrophilic and nucleophilic reagents. The structures of the new products were confirmed based on elemental and spectral analyses. Also, alternative synthetic methods were carried out wherever possible as further evidence for some of the newly synthesized products.

MECHANISM OF CHLORAMINE-T OXIDATION OF METHYL VINYL KETONE AND ISOPROPYL METHYL KETONE IN AQUEOUS ALKALINE MEDIA

Singh, Bharat,Samant, A. K.,Saxena, B. B. L.

, p. 2591 - 2594 (1982)

The oxidation kinetics of methyl vinyl ketone and isopropyl methyl ketone by chloramine-T in aqueous alkaline solutions show first-order dependence on chloramine-T, both substrates and alkali.No effect of p-toluenesulphonamide was evident.Observed stoichiometry, negligible effect of ionic strength and a positive dielectric effect point to a mechanism involving interaction of enolate anions with chloramine-T in the rate determining step.Activation parameters and the isolation of the product formaldehyde are in agreement with the proposed mechanism.

Hot ice computer

Adamatzky, Andrew

, (2009)

We experimentally demonstrate that supersaturated solution of sodium acetate, commonly called 'hot ice', is a massively-parallel unconventional computer. In the hot ice computer data are represented by a spatial configuration of crystallization induction

Photoluminescence as a valuable tool in the optical characterization of acetaminophen and the monitoring of its photodegradation reactions

Baibarac, Mihaela,Daescu, Monica,Ion, Alina C.,Matea, Adelina,Negrila, Catalin,Serbschi, Constantin

, (2020/10/22)

In this work, new evidence for the photodegradation reactions of acetaminophen (AC) is reported by photoluminescence (PL), Raman scattering and FTIR spectroscopy. Under excitation wavelength of 320 nm, AC shows a PL band in the spectral range of 340–550 nm, whose intensity decreases by exposure to UV light. The chemical interaction of AC with the NaOH solutions, having the concentration ranging between 0.001 and 0.3 M, induces a gradual enhancement of the photoluminescence excitation (PLE) and PL spectra, when the exposure time of samples at the UV light increases until 140 min, as a result of the formation of p-aminophenol and sodium acetate. This behavior is not influenced by the excipients or other active compounds in pharmaceutical products as demonstrated by PLE and PL studies. Experimental arguments for the obtaining of p-aminophenol and sodium acetate, when AC has interacted with NaOH, are shown by Raman scattering and FTIR spectroscopy.

ORGANOMETALLIC COMPOUNDS AND METHODS FOR THE DEPOSITION OF HIGH PURITY TIN OXIDE

-

Paragraph 0105, (2019/02/17)

Disclosed herein are compounds useful for the deposition of high purity tin oxide. Also disclose are methods for the deposition of tin oxide films using such compounds. Such films demonstrate high conformality, high etch selectivity and are optically transparent. Such compounds are those of the Formula as follows R x -Sn-A 4-x wherein: A is selected from the group consisting of (Y a R' z ) and a 3- to 7-membered N- containing heterocyclic group; each R group is independently selected from the group consisting of an alkyl or aryl group having from 1 to 10 carbon atoms; each R' group is independently selected from the group consisting of an alkyl, acyl or aryl group having from 1 to 10 carbon atoms; x is an integer from 0 to 4; a is an integer from 0 to 1; Y is selected from the group consisting of N, O, S, and P; and z is 1 when Y is O, S or when Y is absent and z is 2 when Y is N or P.

Manganese-Catalyzed Upgrading of Ethanol into 1-Butanol

Fu, Shaomin,Shao, Zhihui,Wang, Yujie,Liu, Qiang

supporting information, p. 11941 - 11948 (2017/09/07)

Biomass-derived ethanol is an important renewable feedstock. Its conversion into high-quality biofuels is a promising route to replace fossil resources. Herein, an efficient manganese-catalyzed Guerbet-type condensation reaction of ethanol to form 1-butanol was explored. This is the first example of upgrading ethanol into higher alcohols using a homogeneous non-noble-metal catalyst. This process proceeded selectively in the presence of a well-defined manganese pincer complex at the parts per million (ppm) level. The developed reaction represents a sustainable synthesis of 1-butanol with excellent turnover number (>110 000) and turnover frequency (>3000 h-1). Moreover, mechanistic studies including control experiments, NMR spectroscopy, and X-ray crystallography identified the essential role of the "N-H moiety" of the manganese catalysts and the major reaction intermediates related to the catalytic cycle.

Process route upstream and downstream products

Process route

4-nitrophenol acetate
830-03-5

4-nitrophenol acetate

sodium acetate
127-09-3

sodium acetate

Conditions
Conditions Yield
With sodium hydroxide; dibenzo-18-crown-6; In toluene; at 25 ℃; Rate constant; var. alkali, var. catalyst;
With sodium hydroxide; dibenzo-18-crown-6; tetraethylammonium bromide; water; In toluene; at 25 ℃; Rate constant; influence of alkali, phase-transfer catalyst, water, methanol;
With sodium hydroxide; 18-crown-6 ether; In benzene; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; In toluene; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; In xylene; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; In hexane; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; In cyclohexane; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; In 1,4-dioxane; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; In tetrahydrofuran; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; In tetrachloromethane; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; In various solvent(s); at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; In chlorobenzene; at 25 ℃; Rate constant;
With sodium hydroxide; tetraethylammonium bromide; In benzene; at 25 ℃; Rate constant;
With sodium hydroxide; tetraethylammonium bromide; In toluene; at 25 ℃; Rate constant;
With sodium hydroxide; tetraethylammonium bromide; In xylene; at 25 ℃; Rate constant;
With sodium hydroxide; tetraethylammonium bromide; In hexane; at 25 ℃; Rate constant;
With sodium hydroxide; tetraethylammonium bromide; In cyclohexane; at 25 ℃; Rate constant;
With sodium hydroxide; tetraethylammonium bromide; In 1,4-dioxane; at 25 ℃; Rate constant;
With sodium hydroxide; tetraethylammonium bromide; In tetrahydrofuran; at 25 ℃; Rate constant;
With sodium hydroxide; tetraethylammonium bromide; In tetrachloromethane; at 25 ℃; Rate constant;
With sodium hydroxide; tetraethylammonium bromide; In benzonitrile; at 25 ℃; Rate constant;
With sodium hydroxide; tetraethylammonium bromide; In chlorobenzene; at 25 ℃; Rate constant;
With sodium hydroxide; tetraethylammonium bromide; In various solvent(s); at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; tetraethylammonium bromide; In various solvent(s); at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; tetraethylammonium bromide; In xylene; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; tetraethylammonium bromide; In chlorobenzene; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; tetraethylammonium bromide; In benzonitrile; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; tetraethylammonium bromide; In tetrachloromethane; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; tetraethylammonium bromide; In tetrahydrofuran; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; tetraethylammonium bromide; In 1,4-dioxane; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; tetraethylammonium bromide; In cyclohexane; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; tetraethylammonium bromide; In hexane; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; tetraethylammonium bromide; In toluene; at 25 ℃; Rate constant;
With sodium hydroxide; 18-crown-6 ether; tetraethylammonium bromide; In benzene; at 25 ℃; Rate constant;
With N-hexadecyl-N-(2-hydroxyethyl)-N,N-dimethylammonium bromide; sodium hydroxide; In water; at 25 ℃; pH=9.2; Concentration; Reagent/catalyst; Kinetics; Micellar solution;
methyl vinyl ketone
78-94-4,25038-87-3

methyl vinyl ketone

sodium acetate
127-09-3

sodium acetate

Conditions
Conditions Yield
With chloroamine-T; In sodium hydroxide; at 35 ℃; for 48h; Kinetics; Mechanism; Rate constant; ΔE(excit.), ΔS(excit.); different temperatures;
ethanol
64-17-5

ethanol

sodium hydroxide
1310-73-2

sodium hydroxide

sodium acetate
127-09-3

sodium acetate

sodium carbonate
497-19-8

sodium carbonate

Conditions
Conditions Yield
In neat (no solvent); byproducts: H2, CH4; passing alcohol vapor over suoerheated NaOH (reaction starts at 250°C), at same time formation of Na2CO3 via reaction of NaCH3CO2 with NaOH, ratio of products depends on temperature;;
sodium uranyl triacetate

sodium uranyl triacetate

uranyl diacetate
17442-23-8,541-09-3

uranyl diacetate

sodium acetate
127-09-3

sodium acetate

Conditions
Conditions Yield
In neat (no solvent); thermolysis in the absence of O2;
acetic anhydride
108-24-7

acetic anhydride

vinyl acetate
108-05-4,9003-20-7

vinyl acetate

ethylidene diacetate
542-10-9

ethylidene diacetate

sodium acetate
127-09-3

sodium acetate

dimethylglyoxal
431-03-8

dimethylglyoxal

Conditions
Conditions Yield
Produkt 5:Wasserstoff;
1,1,1-tribromoethane
2311-14-0

1,1,1-tribromoethane

vinylidene dibromide
593-92-0

vinylidene dibromide

sodium acetate
127-09-3

sodium acetate

Conditions
Conditions Yield
at 25 ℃; Kinetics;
at 55 ℃; Kinetics;
mercury(II) diacetate
1600-27-7

mercury(II) diacetate

sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

sodium acetate
127-09-3

sodium acetate

phenylmercuric acetate
62-38-4,8013-47-6

phenylmercuric acetate

Conditions
Conditions Yield
byproducts: CH3COOH;
>99
byproducts: CH3COOH;
>99
sodium formate
141-53-7

sodium formate

sodium acetate
127-09-3

sodium acetate

levulinic acid Na-salt
19856-23-6

levulinic acid Na-salt

sodium lactate
312-85-6

sodium lactate

Conditions
Conditions Yield
With tetrasodium phenylporphyrintetrasulphonatoferrate(III); oxygen; sodium hydroxide; In water; at 150 ℃; for 6h; under 15001.5 Torr; Autoclave;
20.07%
49.36%
10.37%
6.84%
10.91%
D-glucose
50-99-7

D-glucose

sodium formate
141-53-7

sodium formate

sodium acetate
127-09-3

sodium acetate

sodium D-gluconate
527-07-1

sodium D-gluconate

Conditions
Conditions Yield
With oxygen; sodium hydroxide; at 150 ℃; for 2h; under 15001.5 Torr; Reagent/catalyst; Autoclave;
38.14%
5.67%
7.7%
9.83%
Conditions
Conditions Yield
With sodium hydroxide; at 145 ℃; for 1h; Product distribution;

Global suppliers and manufacturers

Global( 447) Suppliers
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  • Main Products
  • Country
  • Hangzhou Dingyan Chem Co., Ltd
  • Business Type:Manufacturers
  • Contact Tel:86-571-86465881,86-571-87157530,86-571-88025800
  • Emails:sales@dingyanchem.com
  • Main Products:95
  • Country:China (Mainland)
  • EAST CHEMSOURCES LIMITED
  • Business Type:Manufacturers
  • Contact Tel:86-532-81906761
  • Emails:josen@eastchem-cn.com
  • Main Products:97
  • Country:China (Mainland)
  • Amadis Chemical Co., Ltd.
  • Business Type:Lab/Research institutions
  • Contact Tel:86-571-89925085
  • Emails:sales@amadischem.com
  • Main Products:29
  • Country:China (Mainland)
  • COLORCOM LTD.
  • Business Type:Manufacturers
  • Contact Tel:+86-571-89007001
  • Emails:medkem@medkem.cn
  • Main Products:1
  • Country:China (Mainland)
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