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592-85-8

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592-85-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 592-85-8 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,9 and 2 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 592-85:
(5*5)+(4*9)+(3*2)+(2*8)+(1*5)=88
88 % 10 = 8
So 592-85-8 is a valid CAS Registry Number.
InChI:InChI=1/CHNS.Hg/c2-1-3;/h3H;/q;+2/p-1

592-85-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name MERCURIC THIOCYANATE

1.2 Other means of identification

Product number -
Other names Thiocyanic acid, mercury(2+) salt

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:592-85-8 SDS

592-85-8Synthetic route

mercuric(II) nitrate monohydrate

mercuric(II) nitrate monohydrate

potassium thioacyanate
333-20-0

potassium thioacyanate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
With HNO3 In water aq. soln. of 2 equiv. of KSCN was added to Hg-salt soln. contg. a few drops of 20 % aq. HNO3; crystn. for a several h, crystals were filtered off, washed with H2O anddried;85%
With HNO3 In water aq. KSCN soln. was added to 0.05 equiv. of Hg-salt soln. contg. some drops of 20 % HNO3; soln. was kept for a few hours, crystals were filtered off, washed with H2O and dried;85%
potassium thioacyanate
333-20-0

potassium thioacyanate

mercury dichloride

mercury dichloride

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
In ethanol according standard method: Ramakrishna, R.S and Thuraisingham R., J.Inorg.Nuc.Chem., 35, 285, (1973);80%
In not given excess HgCl2;
In not given excess HgCl2;
n-prSi(NCS)3
18139-82-7

n-prSi(NCS)3

A

n-propyltrichlorosilane
141-57-1

n-propyltrichlorosilane

B

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
With mercury dichloride at careful heating to reflux;;A 65%
B 65%
With HgCl2 at careful heating to reflux;;A 65%
B 65%
thiocyanic acid
463-56-9

thiocyanic acid

mercury fulminate
92114-96-0

mercury fulminate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

thiocyanic acid
463-56-9

thiocyanic acid

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
With mercuri oxide
mercury(II) diacetate
1600-27-7

mercury(II) diacetate

potassium thioacyanate
333-20-0

potassium thioacyanate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

potassium thioacyanate
333-20-0

potassium thioacyanate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
With mercury dichloride
With mercuri nitrate
With mercury dichloride In acetic acid methyl ester excess of KSCN;; precipitation;;
With mercury dichloride In water
With HgCl2 In acetic acid methyl ester excess of KSCN;; precipitation;;
HgSCN

HgSCN

thiocyanato

thiocyanato

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
With carbon disulfide
With tetrachloromethane
Thiocyanate
302-04-5

Thiocyanate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
With mercury dichloride In water concentration: 0.00125-0.1mol/l;;
With HgCl2 In water concentration: 0.00125-0.1mol/l;;
Thiocyanate
302-04-5

Thiocyanate

mercury(II) nitrate

mercury(II) nitrate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
With iron(III) In not given can be used for titrimetric determination of Hg(2+) with Fe(II) as indicator;;
With Fe(3+) In not given can be used for titrimetric determination of Hg(2+) with Fe(II) as indicator;;
Thiocyanate
302-04-5

Thiocyanate

mercury dibromide

mercury dibromide

A

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

B

potassium bromide
7558-02-3

potassium bromide

Conditions
ConditionsYield
In water alkali rhodanide;; not isolated;;
silver thiocyanate
1701-93-5

silver thiocyanate

mercury(II) nitrate

mercury(II) nitrate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
In not given byproducts: {HgSCN}(1+); solving AgSCN in Hg(NO3)2 soln.;;
In not given byproducts: {HgSCN}(1+); solving AgSCN in Hg(NO3)2 soln.;;
mercury(II) cyanide

mercury(II) cyanide

sodium thiosulfate

sodium thiosulfate

A

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

B

sodium thiocyanide
540-72-7

sodium thiocyanide

C

mercury sulfide

mercury sulfide

D

sodium sulfate
7757-82-6

sodium sulfate

E

sodium sulfite
7757-83-7

sodium sulfite

Conditions
ConditionsYield
With sodium oxide In water byproducts: NaCN; in alk. soln.;
With Na2O In water byproducts: NaCN; in alk. soln.;
carbon disulfide
75-15-0

carbon disulfide

nitrogen
7727-37-9

nitrogen

mercury

mercury

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
In neat (no solvent) byproducts: carbon, sulfur; reaction of CS2 vapor with liquid Hg in presence of N2, electrical discharge; a small amt. of Hg(II) thiocyanate forms;;
In neat (no solvent) byproducts: carbon, sulfur; reaction of CS2 vapor with liquid Hg in presence of N2, electrical discharge; a small amt. of Hg(II) thiocyanate forms;;
potassium thioacyanate
333-20-0

potassium thioacyanate

mercury(II) oxide

mercury(II) oxide

A

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

B

potassium hydroxide

potassium hydroxide

Conditions
ConditionsYield
With water In water equilibrium; depending on temp. (25.0-79.0°C); at 99.5°C complete decompn.;
With H2O In water
sodium thiocyanide
540-72-7

sodium thiocyanide

mercury(II) oxide

mercury(II) oxide

A

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

B

sodium hydroxide
1310-73-2

sodium hydroxide

Conditions
ConditionsYield
With water In water equilibrium; depending on temp. (25.0-79.0°C); at 99.5°C complete decompn.;
With H2O In water
phosphoryl-isothiocyanate
1858-25-9

phosphoryl-isothiocyanate

mercury dichloride

mercury dichloride

A

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

potassium thioacyanate
333-20-0

potassium thioacyanate

mercury

mercury

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
In water Electrochem. Process; anodic dissolving of Hg in aq. KSCN soln., favoring by low current density and stirring;;
ammonium thiocyanate

ammonium thiocyanate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
With mercury dichloride In acetic acid methyl ester excess of NH4SCN;; precipitation;;
With HgCl2 In acetic acid methyl ester excess of NH4SCN;; precipitation;;
thiocyanogen
505-14-6

thiocyanogen

mercury(II) iodide

mercury(II) iodide

A

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

B

iodine
7553-56-2

iodine

Conditions
ConditionsYield
In tetrachloromethane
In diethyl ether
In chloroform
potassium thioacyanate
333-20-0

potassium thioacyanate

mercury(II) nitrate

mercury(II) nitrate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
In water immediate reaction;;
In not given addn. of KSCN to Hg(NO3)2 soln.;;
In not given addn. of KSCN to Hg(NO3)2 soln.;;
In water Hg(NO3)2 and KSCN in 1:2 molar ratio; dried in vac. for 30 h;
thiocyanic acid
463-56-9

thiocyanic acid

mercury(II) nitrate

mercury(II) nitrate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
In not given addn. of HSCN to Hg(NO3)2 soln.;;
In not given addn. of HSCN to Hg(NO3)2 soln.;;
Hg(2+)*Cl(1-)*2SCN(1-)={HgCl(SCN)2}(1-)

Hg(2+)*Cl(1-)*2SCN(1-)={HgCl(SCN)2}(1-)

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
With water In water
With H2O In water
sulfinyl isothiocyanate

sulfinyl isothiocyanate

mercury dichloride

mercury dichloride

A

mercurychloridesulfide

mercurychloridesulfide

B

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
In potassium hydroxide aq. KOH;
In sodium hydroxide aq. NaOH;
In potassium hydroxide aq. KOH;
In sodium hydroxide aq. NaOH;
sulfonyl isothiocyanate

sulfonyl isothiocyanate

mercury dichloride

mercury dichloride

A

mercurychloridesulfide

mercurychloridesulfide

B

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
In potassium hydroxide aq. KOH;
In sodium hydroxide aq. NaOH;
In potassium hydroxide aq. KOH;
In sodium hydroxide aq. NaOH;
S2(SCN)2

S2(SCN)2

mercury dichloride

mercury dichloride

A

mercurychloridesulfide

mercurychloridesulfide

B

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
In potassium hydroxide aq. KOH;
In sodium hydroxide aq. NaOH;
In potassium hydroxide aq. KOH;
In sodium hydroxide aq. NaOH;
thiocyanic acid
463-56-9

thiocyanic acid

mercury(II) fulminate

mercury(II) fulminate

A

Hg(2+)*2(SCN)(1-)*2(NH4)(1+)*2(SCN)(1-)=Hg(SCN)2*2NH4SCN

Hg(2+)*2(SCN)(1-)*2(NH4)(1+)*2(SCN)(1-)=Hg(SCN)2*2NH4SCN

B

carbon dioxide
124-38-9

carbon dioxide

C

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

D

mercury sulfide

mercury sulfide

Conditions
ConditionsYield
With persulfocyanic acid In water byproducts: NH3; dissolution in aq. solution of HSCN;
With persulfocyanic acid In water byproducts: NH3; dissolution in aq. solution of HSCN;
ammonium thiocyanate

ammonium thiocyanate

mercury(II) fulminate

mercury(II) fulminate

A

Hg(2+)*2(SCN)(1-)*2(NH4)(1+)*2(SCN)(1-)=Hg(SCN)2*2NH4SCN

Hg(2+)*2(SCN)(1-)*2(NH4)(1+)*2(SCN)(1-)=Hg(SCN)2*2NH4SCN

B

carbon dioxide
124-38-9

carbon dioxide

C

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

D

mercury sulfide

mercury sulfide

Conditions
ConditionsYield
With persulfocyanic acid In water byproducts: NH3;
With persulfocyanic acid In water byproducts: NH3;
{Hg(SCN)4}(2-)

{Hg(SCN)4}(2-)

dimercury(2+)
12596-26-8

dimercury(2+)

A

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

B

mercury(I) thiocyanate

mercury(I) thiocyanate

Conditions
ConditionsYield
In water reaction described in connection with its equlibrium constant;
In water reaction described in connection with its equlibrium constant;
mercury(I) thiocyanate

mercury(I) thiocyanate

dirhodane
1191-10-2

dirhodane

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Conditions
ConditionsYield
In carbon disulfide
In carbon disulfide
tetrahydrofuran
109-99-9

tetrahydrofuran

lanthanum
7439-91-0

lanthanum

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

[La(NCS)3(tetrahydrofuran)4]2

[La(NCS)3(tetrahydrofuran)4]2

Conditions
ConditionsYield
In tetrahydrofuran byproducts: Hg; under N2 using Schlenk techniques; La powder (5.0 mmol) mixed with Hg(SCN)2 (2.5 mmol); thf added; stirred (ambient temp., 5 d); settled; filtered; concd.; crystd. (5°C); elem. anal.;99%
2-methylimidazole
693-98-1

2-methylimidazole

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

(2-methylimidazolyl)HgSCN
93394-91-3

(2-methylimidazolyl)HgSCN

Conditions
ConditionsYield
In water byproducts: HSCN; A mixt. of aq. soln. of reagents was stirred for 3 days;; elem. anal.;98%
In ethanol an ethanolic soln. of ligands was added to a stirred ethanol suspn. of Hg(SCN)2, the mixt. was kept overnight in refrigerator;; water was added; ppt. was filtered; elem. anal.;
mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Hexafluoroacetone
684-16-2

Hexafluoroacetone

Bis<2,2,4,4-tetrakis(trifluormethyl)-4H-1,3,5-dioxazin-6-ylthio>quecksilber
93383-98-3

Bis<2,2,4,4-tetrakis(trifluormethyl)-4H-1,3,5-dioxazin-6-ylthio>quecksilber

Conditions
ConditionsYield
With triethylamine In acetonitrile under exclusion of moisture, (CF3)2CO, CH3CN and some drops Et3N condensed at -196°C to Hg(SCN)2, warmed to room temp., stirred for 24 h; CH3CN removed at E-2 Torr; elem. anal.;98%
1,2,4-Triazole
288-88-0

1,2,4-Triazole

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

(1,2,4-triazolyl)Hg(SCN)
93369-29-0

(1,2,4-triazolyl)Hg(SCN)

Conditions
ConditionsYield
In ethanol an ethanolic soln. of ligand was added to a stirred ethanol suspn. of Hg(SCN)2,; elem. anal.;97%
mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

5-nitroindazole
5401-94-5

5-nitroindazole

(5-nitroindazole)Hg(SCN)2

(5-nitroindazole)Hg(SCN)2

Conditions
ConditionsYield
In ethanol an ethanolic soln. of ligand was added to a stirred ethanol suspn. of Hg(SCN)2, the mixt. was kept for 5 days;; elem. anal.;95%
mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

4′‐(2‐thienyl)‐2,2′;6′,2″‐terpyridine
220525-65-5

4′‐(2‐thienyl)‐2,2′;6′,2″‐terpyridine

dithiocyanato(4'-(2-thienyl)-2,2':6',2''-terpyridine)mercury(II)
1288936-77-5

dithiocyanato(4'-(2-thienyl)-2,2':6',2''-terpyridine)mercury(II)

Conditions
ConditionsYield
In methanol; chloroform Hg(SCN)2 in MeOH added to soln. of ligand in CHCl3; stirred at ambient temp. for 10 min; filtered; ppt. washed with cold MeOH and cold Et2O; dried over silica gel; recrystd. from DMSO-MeOH; elem. anal.;95%
(2,2'-bipyridine)tetracarbonyltungsten(0)
15668-66-3

(2,2'-bipyridine)tetracarbonyltungsten(0)

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

(C5H4NC5H4N)*3(CO)*W*Hg(2+)*2(SCN)(1-)=(C5H4NC5H4N)(CO)3W*{Hg(SCN)2}

(C5H4NC5H4N)*3(CO)*W*Hg(2+)*2(SCN)(1-)=(C5H4NC5H4N)(CO)3W*{Hg(SCN)2}

Conditions
ConditionsYield
In acetone byproducts: CO; to suspn. of W complex in acetone in the dark under N2 added mercury rodanide, stirred at room temp. until CO evolution is complete; filtered, washed with acetone, dried under vac.; elem. anal.;93%
bis(η5-trimethylsilylcyclopentadienyl)bis(trimethylsilylethynyl)-titanium
128247-54-1

bis(η5-trimethylsilylcyclopentadienyl)bis(trimethylsilylethynyl)-titanium

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

A

(C5H4Si(CH3)3)2Ti(NCS)2
82696-64-8

(C5H4Si(CH3)3)2Ti(NCS)2

B

mercury

mercury

Conditions
ConditionsYield
In tetrahydrofuran byproducts: (CH3)3SiCCCCSi(CH3)3; under N2; addn. of Hg(SCN)2 to Ti complex in THF at 0°C, stirring for 30 min at this temp.; filtration through Celite; removal of volatiles in vac. of oil pump, washing residue with cold n-pentane; elem. anal.;A 93%
B n/a
mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Cesium thiocyanate
3879-01-4

Cesium thiocyanate

dicesium tetrakis(thiocyanato)mercurate(II)

dicesium tetrakis(thiocyanato)mercurate(II)

Conditions
ConditionsYield
In ethanol stoich. amts., boiling; crystn. on cooling, collection, washing (EtOH), drying in air; elem. anal.;93%
mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

potassium thioacyanate
333-20-0

potassium thioacyanate

copper(II) acetate monohydrate
6046-93-1

copper(II) acetate monohydrate

ethylenediamine
107-15-3

ethylenediamine

[copper(II)mercury(II)(ethylenediamine)(μ-NCS-N,S)4]

[copper(II)mercury(II)(ethylenediamine)(μ-NCS-N,S)4]

Conditions
ConditionsYield
With malonic acid In methanol; water soln. of Cu salt and malonic acid in distd. H2O heated with stirring to 1/2 vol., cooled to room temp., C2N2H8 added, stirred, then added to soln. of Hg and K salts in MeOH/H2O (3:1, v/v); soln. filtered, left undisturbed at room temp. to ppt.; elem. anal.;93%
mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

Cesium thiocyanate
3879-01-4

Cesium thiocyanate

casium tris(thiocyanato)mercurate(II)

casium tris(thiocyanato)mercurate(II)

Conditions
ConditionsYield
In ethanol stoich. amts., boiling; crystn. on cooling, collection, washing (EtOH), drying in air; can be recrystallized (hot MeOH); elem. anal.;92%
1H-imidazole
288-32-4

1H-imidazole

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

mercury(II) imidazolate

mercury(II) imidazolate

Conditions
ConditionsYield
In water Aq. soln. of reagents were mixed;; elem. anal.;91%
mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

(1,3,5-triaza-7-phosphaadamantane)
53597-69-6

(1,3,5-triaza-7-phosphaadamantane)

PTAHg(SCN)2

PTAHg(SCN)2

Conditions
ConditionsYield
In methanol addn. of hot methanolic soln. of mercury salt to hot methanolic soln. of PTA, molar ratios Hg:PTA 1:2 and 1:1, immediate pptn. of mercury complex, filtered; washed with hot methanol; elem. anal.;90%
9-ethyl-3,6-bis[2-(4-pyridyl)ethenyl]carbazole
437713-19-4

9-ethyl-3,6-bis[2-(4-pyridyl)ethenyl]carbazole

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

(9-ethyl-3,6-bis[2-(4-pyridyl)ethenyl]carbazole)bis(thiocyanate)mercury(II)

(9-ethyl-3,6-bis[2-(4-pyridyl)ethenyl]carbazole)bis(thiocyanate)mercury(II)

Conditions
ConditionsYield
In methanol; dichloromethane soln. of carbazole derivative in CH2Cl2 layered onto soln. of Hg(SCN)2 in CH3OH, stored for several d; crystals isolated; elem. anal.;90%
mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

1-hydrosilatrane

1-hydrosilatrane

1-isothiocyanato-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane
187027-67-4

1-isothiocyanato-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane

Conditions
ConditionsYield
In o-xylene at 20℃; for 1h;90%
2-iodo-2-trifluoromethylperfluoropentane
102780-88-1

2-iodo-2-trifluoromethylperfluoropentane

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

1,1,1,2,2,3,3,5,5,5-Decafluoro-4-thiocyanato-4-trifluoromethyl-pentane
125510-68-1

1,1,1,2,2,3,3,5,5,5-Decafluoro-4-thiocyanato-4-trifluoromethyl-pentane

Conditions
ConditionsYield
89%
potassium hydridotris(3,5-dimethylpyrazolyl)borate
17567-17-8

potassium hydridotris(3,5-dimethylpyrazolyl)borate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

{hydrotris(3,5-dimethyl-1-pyrazolyl)borato}thiocyanatomercury(II)

{hydrotris(3,5-dimethyl-1-pyrazolyl)borato}thiocyanatomercury(II)

Conditions
ConditionsYield
In dichloromethane under stirring; filtered, dried in vacuo until constant weight (20°C, 0.1 Torr), recrystd. (CH2Cl2-Et2O); elem. anal.;89%
tetracarbonyl(2,9-dimethyl-1,10-phenanthroline)tungsten(0)
22718-70-3

tetracarbonyl(2,9-dimethyl-1,10-phenanthroline)tungsten(0)

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

(C6H5NC2H2C6H5N)*3(CO)*W*Hg(2+)*2{(SCN)(1-)}={(C6H5NC2H2C6H5N)(CO)3W}*{Hg(2+)*2(SCN)(1-)}

(C6H5NC2H2C6H5N)*3(CO)*W*Hg(2+)*2{(SCN)(1-)}={(C6H5NC2H2C6H5N)(CO)3W}*{Hg(2+)*2(SCN)(1-)}

Conditions
ConditionsYield
In acetone byproducts: CO; to suspn. of W complex in acetone in the dark under N2 added mercury rodanide, stirred at room temp. until CO evolution is complete; filtered, washed with acetone, dried under vac.; elem. anal.;89%
(C12H8N2)(CO)3(C5H5N)Mo
15200-35-8

(C12H8N2)(CO)3(C5H5N)Mo

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

(C12H8N2)(CO)3MoHg(SCN)2
92451-74-6

(C12H8N2)(CO)3MoHg(SCN)2

Conditions
ConditionsYield
In acetone under N2, in the absence of light, molar ratio complex:Hg(SCN)2=1:1, stirred for several minutes in the dark; filtered off, washed with acetone, dried in vac., elem. anal.;88%
4-[4-(dimethylamino)phenyl]-2,6-bis(4-pyridinyl)pyridine

4-[4-(dimethylamino)phenyl]-2,6-bis(4-pyridinyl)pyridine

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

2CNS(1-)*Hg(2+)*C23H20N4

2CNS(1-)*Hg(2+)*C23H20N4

Conditions
ConditionsYield
In methanol; dichloromethane at 20℃; for 168h; Sealed tube;87.3%
ruthenium Cl(CO)(NO)(P(C6H5)3)2

ruthenium Cl(CO)(NO)(P(C6H5)3)2

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

{Ru(SCN)2(HgSCN)(CO)(NO)(P(C6H5)3)}

{Ru(SCN)2(HgSCN)(CO)(NO)(P(C6H5)3)}

Conditions
ConditionsYield
In ethanol; dichloromethane under N2, refluxed for 2 h; collected, washed (CH2Cl2, EtOH and Et2O); elem. anal.;87%
tetracarbonyl(1,10-phenanthroline)tungsten(0)
14729-20-5

tetracarbonyl(1,10-phenanthroline)tungsten(0)

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

(C5H3NC2H2C5H3N)*3(CO)*W*Hg(2+)*2(SCN)(1-)=(C5H3NC2H2C5H3N)(CO)3W*{Hg(SCN)2}

(C5H3NC2H2C5H3N)*3(CO)*W*Hg(2+)*2(SCN)(1-)=(C5H3NC2H2C5H3N)(CO)3W*{Hg(SCN)2}

Conditions
ConditionsYield
In acetone byproducts: CO; to suspn. of W complex in acetone in the dark under N2 added mercury rodanide, stirred until CO evolution is complete; filtered, washed with acetone, dried under vac.; elem. anal.;87%
lanthanum
7439-91-0

lanthanum

1,2-dimethoxyethane
110-71-4

1,2-dimethoxyethane

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

[La(NCS)3(1,2-dimethoxyethane)3]

[La(NCS)3(1,2-dimethoxyethane)3]

Conditions
ConditionsYield
In 1,2-dimethoxyethane byproducts: Hg; under N2 using Schlenk techniques; La powder (6.3 mmol) mixed with Hg(SCN)2 (3.1 mmol); dme added; stirred (ambient temp., 3 d); settled; filtered; concd.; heated; dme added; filtered; crystd. (5°C); washed with toluene; elem. anal.;87%
1,2-dimethoxyethane
110-71-4

1,2-dimethoxyethane

[Yb(NCS)2(tetrahydrofuran)2]

[Yb(NCS)2(tetrahydrofuran)2]

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

[Yb(NCS)3(1,2-dimethoxyethane)2]

[Yb(NCS)3(1,2-dimethoxyethane)2]

Conditions
ConditionsYield
In 1,2-dimethoxyethane byproducts: Hg; under N2 using Schlenk techniques; Yb(NCS)2(thf)2 (0.46 mmol) mixed withHg(SCN)2 (0.23 mmol); stirred (room temp., 3 d); settled; filtered; concd.; toluene added; crystd. (room temp., 1 wk); elem. anal.;87%
2-isopropylimidazole
36947-68-9

2-isopropylimidazole

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

(2-isopropylimidazole)2Hg(SCN)2

(2-isopropylimidazole)2Hg(SCN)2

Conditions
ConditionsYield
In ethanol an ethanolic soln. of ligands was added to a stirred ethanol suspn. of Hg(SCN)2, the mixt. was kept overnight in refrigerator;; water was added; ppt. was filtered; elem. anal.;86%
ammonium thiocyanate

ammonium thiocyanate

phenyl(pyridin-2-yl)methanone
91-02-1

phenyl(pyridin-2-yl)methanone

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

copper dichloride

copper dichloride

[CuHg(2-benzoylpyridine)(thiocyanate)4]n

[CuHg(2-benzoylpyridine)(thiocyanate)4]n

Conditions
ConditionsYield
In methanol; water dissolving mixt. of ammonium and mercury thiocyanates in water, addn. tomethanolic soln. of copper compd. and pyridine deriv., stirring at room m temp. for 2 h; filtration, drying, recrystn. (methanol), elem. anal.;85%
ammonium thiocyanate

ammonium thiocyanate

copper(II) choride dihydrate

copper(II) choride dihydrate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

bis(pyrazol-1-yl)methane
27258-04-4

bis(pyrazol-1-yl)methane

[Cu(bis(pyrazol-1-yl)methane)Hg(SCN)4]n

[Cu(bis(pyrazol-1-yl)methane)Hg(SCN)4]n

Conditions
ConditionsYield
In methanol; water NH4SCN, Hg(SCN)2 dissolved in H2O, slowly added to MeOH soln. of CuCl2*2H2O and bis(pyrazol-1-yl)methane, stirred at room temp. for 6 h; filtered, dried in air, slowly recrystd. from MeOH; elem. anal.;85%
ammonium thiocyanate

ammonium thiocyanate

copper(II) choride dihydrate

copper(II) choride dihydrate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

bis(pyrazol-1-yl)methane
27258-04-4

bis(pyrazol-1-yl)methane

[Cu(bis(pyrazol-1-yl)methane)2Hg(thiocyanato)4]

[Cu(bis(pyrazol-1-yl)methane)2Hg(thiocyanato)4]

Conditions
ConditionsYield
In methanol; water NH4SCN and Hg(SCN)2 dissolved in H2O; added slowly to MeOH soln. of Cu salt and ligand; stirred at room temp. for 6 h; filtered; ppt. dried in air; elem. anal.;85%
ammonium thiocyanate

ammonium thiocyanate

manganese(II) chloride tetrahydrate

manganese(II) chloride tetrahydrate

mercury(II) thiocyanate
592-85-8

mercury(II) thiocyanate

bis(pyrazol-1-yl)methane
27258-04-4

bis(pyrazol-1-yl)methane

[Mn(bis(pyrazol-1-yl)methane)Hg(SCN)4](n)

[Mn(bis(pyrazol-1-yl)methane)Hg(SCN)4](n)

Conditions
ConditionsYield
In methanol; water NH4SCN and Hg(SCN)2 dissolved in H2O; slowly added to MeOH soln. of Mn salt and ligand; stirred at room temp. for 6 h; filtered; ppt. dried in air; elem. anal.;85%

592-85-8Relevant articles and documents

Synthesis, spectroscopic and structural investigation of Zn(NCS)2(nicotinamide)2 and [Hg(SCN)2(nicotinamide)]n

Dakovi?, Marijana,Popovi?, Zora,Giester, Gerald,Raji?-Linari?, Ma?a

, p. 465 - 472 (2008)

Zinc(II) and mercury(II) thiocyanate complexes with nicotinamide, bis(nicotinamide-N)-bis(thiocyanato-N)zinc(II) (1) and catena-[nicotinamide-N-(μ-thiocyanato-S,N)(thiocyanato-S)mercury(II)] (2), have been prepared and characterized by spectroscopic, ther

Mercury(II) complexes of heterocyclic thiones. Part 1. Preparation of 1:2 complexes of mercury(II) halides and pseudohalides with 3,4,5,6-tetrahydropyrimidine-2-thione. X-ray, thermal analysis, and NMR studies

Popovi?, Zora,Pavlovi?, Gordana,Matkovi?-?alogovi?, Dubravka,Soldin, ?eljka,Raji?, Ma?a,Viki?-Topi?, Dra?en,Kova?ek, Damir

, p. 142 - 152 (2000)

A series of complexes HgX2(H4pymtH)2 (X = Cl-, Br- I-, SCN-, CN- ; H4pymtH = 3,4,5,6-tetrahydropyrimidine-2-thione) has been obtained by the reaction of H4pymtH with mercury(II) halides and pseudohalides in the molar ratio 2:1. X-ray diffraction studies revealed tetrahedral coordination of mercury with S-bound H4pymtH. The exception is Hg(CN)2(H4pymtH)2 where the coordination is 2 + 2 with two strongly bound CN- ligands and weaker H-S bonds with H4pymtH. One- and two-dimensional 1H and 13C NMR measurements in dimethylsulfoxide solution confirmed the complexation of mercury to sulfur. The greatest complexation effects on chemical shifts were detected for the C-2, C-5 and H-1,3 atoms, i.e. two, four and five bonds away from mercury atom. The complexation effects in Hg(SCN)2(H4pymtH)2 and Hg(CN)2(H4pymtH)2 are in agreement with the strongest intramolecular H-bonding in the former and the weakest Hg-S bonds in the latter as compared to other complexes here. (C) 2000 Elsevier Science S.A.

Smith, G. B. L.,Warttman, P.,Browne, A. W.

, p. 2806 - 2810 (1930)

Structures from powders: Polynuclear Hg(11) complexes containing the flexible bisimidazolylmethane ligand

Masciocchi, Norberto,Albisetti, Alessandro Figini,Sironi, Angelo,Pettinari, Claudio,Nicola, Corrado Di,Pettinari, Riccardo

, p. 5328 - 5337 (2009)

Several polynuclear Hg(11) complexes containing the flexible ditopic bisimidazolylmethane ligand (C7H8N4, bim) have been prepared by reaction of equimolar quantities of mercury salts (acetate, cyanide, thiocyanate, chlorid

Burriel, F.,Lucena, F.

, p. 344 - 350 (1950)

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