592-85-8Relevant articles and documents
Synthesis, spectroscopic and structural investigation of Zn(NCS)2(nicotinamide)2 and [Hg(SCN)2(nicotinamide)]n
Dakovi?, Marijana,Popovi?, Zora,Giester, Gerald,Raji?-Linari?, Ma?a
, p. 465 - 472 (2008)
Zinc(II) and mercury(II) thiocyanate complexes with nicotinamide, bis(nicotinamide-N)-bis(thiocyanato-N)zinc(II) (1) and catena-[nicotinamide-N-(μ-thiocyanato-S,N)(thiocyanato-S)mercury(II)] (2), have been prepared and characterized by spectroscopic, ther
Mercury(II) complexes of heterocyclic thiones. Part 1. Preparation of 1:2 complexes of mercury(II) halides and pseudohalides with 3,4,5,6-tetrahydropyrimidine-2-thione. X-ray, thermal analysis, and NMR studies
Popovi?, Zora,Pavlovi?, Gordana,Matkovi?-?alogovi?, Dubravka,Soldin, ?eljka,Raji?, Ma?a,Viki?-Topi?, Dra?en,Kova?ek, Damir
, p. 142 - 152 (2000)
A series of complexes HgX2(H4pymtH)2 (X = Cl-, Br- I-, SCN-, CN- ; H4pymtH = 3,4,5,6-tetrahydropyrimidine-2-thione) has been obtained by the reaction of H4pymtH with mercury(II) halides and pseudohalides in the molar ratio 2:1. X-ray diffraction studies revealed tetrahedral coordination of mercury with S-bound H4pymtH. The exception is Hg(CN)2(H4pymtH)2 where the coordination is 2 + 2 with two strongly bound CN- ligands and weaker H-S bonds with H4pymtH. One- and two-dimensional 1H and 13C NMR measurements in dimethylsulfoxide solution confirmed the complexation of mercury to sulfur. The greatest complexation effects on chemical shifts were detected for the C-2, C-5 and H-1,3 atoms, i.e. two, four and five bonds away from mercury atom. The complexation effects in Hg(SCN)2(H4pymtH)2 and Hg(CN)2(H4pymtH)2 are in agreement with the strongest intramolecular H-bonding in the former and the weakest Hg-S bonds in the latter as compared to other complexes here. (C) 2000 Elsevier Science S.A.
Smith, G. B. L.,Warttman, P.,Browne, A. W.
, p. 2806 - 2810 (1930)
Structures from powders: Polynuclear Hg(11) complexes containing the flexible bisimidazolylmethane ligand
Masciocchi, Norberto,Albisetti, Alessandro Figini,Sironi, Angelo,Pettinari, Claudio,Nicola, Corrado Di,Pettinari, Riccardo
, p. 5328 - 5337 (2009)
Several polynuclear Hg(11) complexes containing the flexible ditopic bisimidazolylmethane ligand (C7H8N4, bim) have been prepared by reaction of equimolar quantities of mercury salts (acetate, cyanide, thiocyanate, chlorid
Burriel, F.,Lucena, F.
, p. 344 - 350 (1950)