Reactivity of cis-{PtII(Ar)(alkyne)} fragments (Ar = aryl): A domino-formation of indenes

DOI: 10.1021/om701239b

Source and publish data:

Organometallics p. 1351 - 1353 (2008)

Update date:2022-08-02

Topics:

Authors:

Cucciolito, Maria Elena

De Renzi, Augusto

Roviello, Giuseppina

Ruffo, Francesco

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Article abstract of DOI:10.1021/om701239b

The reactivity of cis-{Pt^II(Ar)(2-butyne)] fragments in cationic complexes is described. Coordination of the unsaturated ligand is observed at low temperature. Upon increasing at 298 K, a cascade of reactions affords a selective formation of indenes. Mechanistic implications of this domino-reaction are discussed.

Full text of DOI:10.1021/om701239b

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