REGIOSELECTIVITY IN REACTIONS OF ALKYNYLMETAL COMPLEXES WITH PYRIMIDINONES

DOI: 10.1016/0022-328X(85)80160-1

Source and publish data:

Journal of Organometallic Chemistry p. 139 - 144 (1985)

Update date:2022-08-04

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Authors:

Rise, Frode

Undheim, Kjell

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Article abstract of DOI:10.1016/0022-328X(85)80160-1

Regioselectivity is observed in 1/1-adduct formation between phenylethynyltriisopropoxytitanium and 2(1H)-pyrimidinones; the new carbon-carbon bond is formed at C(4).In contrast the 3,4- and 3,6-dihydro products are formed together from the corresponding

Full text of DOI:10.1016/0022-328X(85)80160-1

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Product name:1-benzyl-3,6-dihydro-6-phenylethynyl-2(1H)-pyrimidinone

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