NICKEL ENOLATES IN THE Ni(CO)4-INDUCED CARBONYLATION OF GEM-DIBROMOCYCLOPROPANES WITH SILYLAMINE OR SILYLSULFIDE

DOI: 10.1016/S0040-4039(01)80853-4

Source and publish data:

Tetrahedron Letters p. 5061 - 5064 (1985)

Update date:2022-07-30

Topics:

Authors:

Hirao, Toshikazu

Nagata, Shinichiro

Yamana, Yoshihiro

Agawa, Toshio

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Article abstract of DOI:10.1016/S0040-4039(01)80853-4

Silyl compounds (N,N-dialkyltrimethylsilylamine, 1-(trimethylsilyl)-imidazole and phenylthiotrimethylsilane) were successfully used in the Ni(CO)4-induced carbonylation reactions of gem-dibromocyclopropanes.The nickel carbenoid and enolate complexes are c

Full text of DOI:10.1016/S0040-4039(01)80853-4

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