Some Molecular Hydrogen Complexes of Iridium

DOI: 10.1021/ja00274a030

Source and publish data:

Journal of the American Chemical Society p. 4032 - 4037 (1986)

Update date:2022-08-02

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Authors:

Crabtree, Robert H.

Lavin, Maryellen

Bonneviot, L.

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Article abstract of DOI:10.1021/ja00274a030

The new molecular hydrogen complexes ⁺ (bq = 7,8-benzoquinolinate, L = PPh3 or PCy3) and ⁺ are described.A 1H NMR T₁ criterion is proposed for detecting such complexes.Deprotonation of the coordinated H2 is described.The mechanism of hydrogenolysis of d⁰ alkyls is discussed and a dihydrogen complex proposed as intermediate.

Full text of DOI:10.1021/ja00274a030

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