Some Molecular Hydrogen Complexes of Iridium

DOI: 10.1021/ja00274a030

Source and publish data:

Journal of the American Chemical Society p. 4032 - 4037 (1986)

Update date:2022-08-02

Topics:

Authors:

Crabtree, Robert H.

Lavin, Maryellen

Bonneviot, L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00274a030

The new molecular hydrogen complexes ⁺ (bq = 7,8-benzoquinolinate, L = PPh3 or PCy3) and ⁺ are described.A 1H NMR T₁ criterion is proposed for detecting such complexes.Deprotonation of the coordinated H2 is described.The mechanism of hydrogenolysis of d⁰ alkyls is discussed and a dihydrogen complex proposed as intermediate.

Full text of DOI:10.1021/ja00274a030

Products guided by the article

Product name:C₄₉H₄₁IrNP₂⁽¹⁺⁾

Cas No:102493-44-7

R&D Labs maybe for 102493-44-7

Zibo Fuxi'er Chemical Co.,Ltd （Shanxian Fuxi'er Chemical Co.,Ltd）

Contact:+86-533-2091422

Address:Eastern 4 on the 3th Road ,Liangxiang Industrial Park, Zibo city ,Shandong,China
Brichem ( Haikou ) Co. Ltd.

Contact:86-898-65311214

Address:Room 102, BLDG. 68 Jiangnan City, No. 66 Heping Road,Haikou, Hainan, China
Yingkou Sanzheng Organic Chemical Co. Ltd.

Contact:+86-417-3638818

Address:25 Gengxinli Village, Daqing Road, Yingkou, Liaoning, China
Jiangxi Huashi Pharmaceutical Co., Ltd

Contact:+86-795-4509628

Address:Ningbo Ave., Fengtian Industrial Park, Fengxin Country, Jiangxi, China.
Huayi Isotopes Co.

Contact:+ 86 512 52491118

Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China

Relevant to this article

Minor and trace sterols in marine invertebrates 55. The isolation, structure elucidation and synthesis of ergosta-5,24(28),25-trien-3β-ol

Doi:10.1016/0039-128X(85)90009-1
(1985)
Novel multi-branched organic compounds with enhanced two-photon absorption benefiting from the strong electronic coupling

Doi:10.1016/j.cplett.2005.08.041
(2005)
Some Preparatively Useful <4+2>Cycloadditions of 6,6-Diphenylfulvene

Doi:10.1055/s-1985-31356
(1985)
Iminophosphorane-mediated efficient synthesis of new tricyclic 3,5-dihydro-1,2,3-triazolo[4,5-d]-1,2,4-triazolo[1,5-a]pyrimidin-9-ones

Doi:10.1039/b513715b
(2006)
Palladium mediated total synthesis of o-acetylphenylacetic acids: A general route to indolo[2,3-b]naphthalene-6,11-diones

Doi:10.1016/S0040-4039(01)00884-X
(2001)
An improved approach to chiral cyclopentenone building blocks. Total synthesis of pentenomycin I and neplanocin A

Doi:10.1021/jo050987t
(2005)

Article Doi