Facile Bridged Bicycloalkane Synthesis via Intramolecular Nitrone-Olefin Cycloaddition

DOI: 10.1021/jo00163a052

Source and publish data:

Journal of Organic Chemistry p. 2632 - 2634 (1983)

Update date:2022-08-02

Topics:

Authors:

Funk, Raymond L.

Horcher, Linus H. M.

Daggett, Joy Umstead

Hansen, Marvin M.

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Article abstract of DOI:10.1021/jo00163a052

Exocyclic nitrones smoothly participate in intramolecular cycloaddition reactions to provide bridged bicycloalkanes.The application of this methodology in the first total synthesis of the antifertility agent (+/-)-7,12-secoishwaran-12-ol is also discussed

Full text of DOI:10.1021/jo00163a052

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