
Tetrahedron Letters p. 5443 - 5444 (1985)
Update date:2022-07-30
Topics:
Labaudiniere, L
Burgada, R.
We describe the first orthoalkylation of a phenoxyvinylphosphorane leading to a spirophosphorane.At 160 deg C, the reaction is fast and stereoselective.When the ortho positions are substituted, a non stereoselective paraalkylation occurs.
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Doi:10.1016/S0040-4020(01)96735-3
(1985)Doi:10.1021/ja01509a044
(1960)Doi:10.1021/jo801021f
(2008)Doi:10.1016/j.tetlet.2008.05.089
(2008)Doi:10.1021/acsmedchemlett.0c00338
(2021)Doi:10.1021/ic800690z
(2008)