Tetrahedron Letters p. 5443 - 5444 (1985)
Update date:2022-07-30
Topics:
Labaudiniere, L
Burgada, R.
We describe the first orthoalkylation of a phenoxyvinylphosphorane leading to a spirophosphorane.At 160 deg C, the reaction is fast and stereoselective.When the ortho positions are substituted, a non stereoselective paraalkylation occurs.
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Doi:10.1016/S0040-4020(01)96735-3
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