ORTHOALKYLATION SUR LE NOYAU AROMATIQUE D'UN PHENOXYVINYLPHOSPHORANE

DOI: 10.1016/S0040-4039(00)98230-3

Source and publish data:

Tetrahedron Letters p. 5443 - 5444 (1985)

Update date:2022-07-30

Topics:

Authors:

Labaudiniere, L

Burgada, R.

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Article abstract of DOI:10.1016/S0040-4039(00)98230-3

We describe the first orthoalkylation of a phenoxyvinylphosphorane leading to a spirophosphorane.At 160 deg C, the reaction is fast and stereoselective.When the ortho positions are substituted, a non stereoselective paraalkylation occurs.

Full text of DOI:10.1016/S0040-4039(00)98230-3

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