Journal of Organometallic Chemistry p. 51 - 62 (1985)
Update date:2022-09-26
Topics:
Lotz, Simon
Schindehutte, Minet
Dyk, Marthime M. van
Dillen, Jan L. M.
Rooyen, Petrus H. van
A carbonyl ligand of ?-arenetricarbonylchromium(0) complexes is photochemically displaced to give ?-arenedicarbonyl complexes of chromium(0) with thio-ether ligands.In contrast, irradiation of ?-arenetricarbonylchromium compounds with dithio-ester and trithiocarbonate ligands yields only pentacarbonyl complexes.Substitution of the ?-arene ring, the thio-ether ligand, or both, is easily achieved at room temperature and in polar solvents.The crystal structure of cis-teracarbonyl(methyl-1,3-dithian-2-methyl-2-dithiocarboxylate)chromium(0) shows remarkably similar Cr-S bond distances of 2.379(2) and 2.383(2) Angstroem for the respective thio-ether and dithio-ester sulphur-donor atoms of bidentate ligand.
Shandong Yaroma Perfumery Co., Ltd.
Contact:+86- 531- 88024598
Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
Contact:+31-24-3886056
Address:Binderskampweg 29 Unit 36
NIGNXIA XINDACHANG TECHNOLOGY CO.,LTD
Contact:86-0951-7815345
Address:North side of Qiyuan Road, west side of Yuanfeng Highway, New Material Park, Ningdong Energy and Chemical Industry Base, Ningxia,China
Weifang Arylchem Chemical Co., LTD
Contact:86-536-5217866
Address:Development Zone, Shouguang, Shandong Province
Jinzhou Jiutai Pharmaceutical Co.,Ltd
Contact:+86-0416-5179890
Address:No.41, Taianli, Taihe District, Jinzhou, Liaoning
Doi:10.1016/0040-4020(76)88006-4
(1976)Doi:10.1016/S0960-894X(03)00697-8
(2003)Doi:10.1016/S0022-328X(00)93362-X
(1972)Doi:10.1016/0040-4039(76)80079-2
(1976)Doi:10.1002/jhet.5570390530
(2002)Doi:10.1039/jr9590001902
(1959)
