Journal of Organic Chemistry p. 5498 - 5499 (1986)
Update date:2022-08-16
Topics: alkenes Alkynes Radical Initiation Free radical reactions Radical Propagation Radical Termination
Russell, Glen A.
Jiang, Wan
Hu, Shui Sheng
Khanna, Rajive K.
Substituted acetylenes or electronegatively monosubstituted ethylenes react with t-BuHgCl in photostimulated free radical chain processes in PhH or Me2SO to form R1C(t-Bu)+C(HgCl)R2 (R1, R2 = H, Ph; H, COMe; EtO2C, Ph; EtO2C, EtO2C) or t-BuCH2CH(HgCl)E (E
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Doi:10.1139/v86-252
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