Free Radical Reactions of Organomercury Halides with Alkenes and Alkynes

DOI: 10.1021/jo00376a107

Source and publish data:

Journal of Organic Chemistry p. 5498 - 5499 (1986)

Update date:2022-08-16

Topics: alkenes Alkynes Radical Initiation Free radical reactions Radical Propagation Radical Termination

Authors:

Russell, Glen A.

Jiang, Wan

Hu, Shui Sheng

Khanna, Rajive K.

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Article abstract of DOI:10.1021/jo00376a107

Substituted acetylenes or electronegatively monosubstituted ethylenes react with t-BuHgCl in photostimulated free radical chain processes in PhH or Me2SO to form R1C(t-Bu)+C(HgCl)R2 (R1, R2 = H, Ph; H, COMe; EtO2C, Ph; EtO2C, EtO2C) or t-BuCH2CH(HgCl)E (E

Full text of DOI:10.1021/jo00376a107

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