Free Radical Reactions of Organomercury Halides with Alkenes and Alkynes

DOI: 10.1021/jo00376a107

Source and publish data:

Journal of Organic Chemistry p. 5498 - 5499 (1986)

Update date:2022-08-16

Topics: alkenes Alkynes Radical Initiation Free radical reactions Radical Propagation Radical Termination

Authors:

Russell, Glen A.

Jiang, Wan

Hu, Shui Sheng

Khanna, Rajive K.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00376a107

Substituted acetylenes or electronegatively monosubstituted ethylenes react with t-BuHgCl in photostimulated free radical chain processes in PhH or Me2SO to form R1C(t-Bu)+C(HgCl)R2 (R1, R2 = H, Ph; H, COMe; EtO2C, Ph; EtO2C, EtO2C) or t-BuCH2CH(HgCl)E (E

Full text of DOI:10.1021/jo00376a107

Products guided by the article

Product name:Benzene, (1-iodo-3,3-dimethyl-1-butenyl)-

Cas No:105817-80-9

R&D Labs maybe for 105817-80-9

Shandong Yuanli Science and Technology Co., Ltd.

Contact:86-0536-6777557

Address:Zhuliu Industiral Park,Changle County
Synochem Ingredients Corp., Ltd.

Contact:+86-512-5636 2180

Address:Zhangjiagang Free Trade Zone
Anqing World Chemical Co., Ltd.

Contact:+86-556-5800026

Address:Daguan Economic Development Zone of circular economy industrial park Anqing City Anhui province
Jiangxi Dongxu Chemical Science & Technology Co.,Ltd

Contact:+86-791-86899381

Address:Nanchang, Jiangxi, China
Beijing Stable Chemcial Co.ltd

Contact:86-10-63785052

Address:A1301 Technological Edifice. No.4 FuFeng Road,FengTai District, Beijing. China

Relevant to this article

Vitamin D relatives. Part I. B-thiophene-des-A-cholestanes. Solvolytic reactions of some derivatives of 2,2-disubstituted cyclohexane-1,4-diol and 4-hydroxycyclohexan-1-one

Doi:10.1139/v86-252
(1986)
Nickel phosphide nanocatalysts for the chemoselective hydrogenation of alkynes

Doi:10.1016/j.nantod.2011.12.003
(2012)
The Mannich reaction in the synthesis of N,S-containing heterocycles 6. New approaches to the synthesis of pyrimido[4,3-b][1,3,5]thiadiazine derivatives

Doi:10.1007/s11172-007-0226-6
(2007)
Studies on cardiac ingredients of plants. XI. synthesis of new bufotoxin homologues utilizing scillarenin (the genuine aglycone of proscillaridin), and their biological activities

Doi:10.1248/cpb.42.2256
(1994)
Copper-Mediated Trifluoroacetylation of Arenediazonium Salts with Ethyl Trifluoropyruvate

Doi:10.1002/chem.201604300
(2016)
Palladium-catalyzed 1,4-addition of terminal alkynes to unsaturated carbonyl compounds promoted by electron-rich ligands

Doi:10.1039/b805946m
(2008)

Article Doi