Journal of Organic Chemistry p. 1417 - 1421 (1987)
Update date:2022-07-29
Topics:
Parpani, Patrizia
Zecchi, Gaetano
The reaction of the title nitrone with (phenylsulfonyl)alkynes 1a,b results in 3-acylindoles 6a,b via unstable 4-isoxazoline cycloadducts which evolve by fission of the N-O bond and subsequent reclosure onto the ortho position of the N-phenyl substituent.Under the same conditions, the title nitrone reacts with (phenylsulfonyl)propadiene (10) to give the isomeric benzazepinone 12 and pyrrolidone 11, both of which are presumably formed from a common, transient cycloadduct.Compound 12 changes readily through a novel pathway leading to the indole derivative 14.
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