Tetrahedron p. 4685 - 4690 (1986)
Update date:2022-07-30
Topics:
Mori, Kenji
Ebata, Takashi
(2S,3R,1'S,2'S)-Stegobiol 1, a new pheromone component of Stegobium paniceum L., was synthesized with stereocontrol at C-2, C-1' and C-2', starting from ethyl (R)-3-hydroxybutanoate and methyl (S)-3-hydroxypentanoate.The stereochemistry of the naturally occuring 1 was confirmed to be 2S,3R,1'S,2'S by the present synthesis.
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