
Tetrahedron Letters p. 5495 - 5496 (1986)
Update date:2022-09-26
Topics:
Gosselin, Pascal
A new synthetic route to γ-damascone 1 starting from methyl-γ-dithiocyclogeranate 2 is described.Addition of HMPT is found necessary to perform the reaction of allylmagnesium bromide with dithioester 2.A new, mild hydrolysis method is developped in order to transform the resulting vinylsulfide 4 into 1.
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