Total Synthesis of the Sesterterpenoid (+/-)-Palauolide

DOI: 10.1039/c39870001342

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1342 - 1343 (1987)

Update date:2022-08-04

Topics: Yield NMR spectroscopy Catalyst Stereochemistry Chromatography Total synthesis Chemical Synthesis Isoprene unit

Authors:

Piers, Edward

Wai, John S. M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870001342

Transformation of 3,6-dimethylcyclohex-2-enone (2) into the sesterterpenoid (+/-)-palauolide (1) was accomplished via a 17-step sequence of reactions.

Full text of DOI:10.1039/c39870001342

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:4-(phenylsulfonylmethyl)-2-trimethylsilylfuran

Cas No:115376-49-3

R&D Labs maybe for 115376-49-3

Hubei ShiNan Pharmaceutical Chemical co., Ltd.(expird)

Contact:+86-13554447107

Address:Wuhan HongShanOu wu no road 378 future residence building 1 unit 14 layer no. 1401 A
PharmOrgsyn

Contact:+86-21-38228826

Address:Room 505 Building 2, No 3377 Kangxin Highway, Shanghai, Republic China
Beijing Century Richap Chemistry Co.,Ltd

Contact:+86- 010-64455497

Address:Guannan County, Lianyungang City, Jiangsu Province, China
YanCheng LongShen Chemical Co.,Ltd.

Contact:+86-515-86668866

Address:No.13,Weiyi Road,Funing Aoyang Industrial Park
Jiangsu Cale New Material Co.ltd

Contact:+86-515-88334667/88203550

Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China

Relevant to this article

Highly diastereoselective reduction of α-alkyl-β-hydroxy ketones with sodium and lithium boron hydrides via their titanium alcoholates

Doi:10.1016/S0040-4039(99)00308-1
(1999)
Synthesis and Structure of a Semi-rigid Dinucleating Macrocycle containing the 2,6-Bis(thiomethyl)pyridine Unit and Reactions of its Copper(II) Complex

Doi:10.1039/c39880000579
(1988)
A Trimer of ultrafast nanomotors: synthesis, photochemistry and self-assembly on graphite

Doi:10.1002/chem.200802718
(2009)
A convergent route for the total synthesis of malyngamides O, P, Q, and R

Doi:10.1021/jo9003103
(2009)
Doi:10.1021/ja01549a090
(1958)
Lower rim calix(4)arene ketone derivatives and their interaction with alkali metal cations. Structural and thermodynamic (solution and complexation) characterisation of the tetraphenyl ketone derivative and its sodium complex

Doi:10.1039/b104355m
(2001)

Article Doi