
Tetrahedron p. 3987 - 3996 (1987)
Update date:2022-07-31
Topics:
Schneider,Gyula
Hackler,Laszlo
Sohar,Pal
In the DMSO/NaHCO3 system, 16α-aminomethyl-, 16α-benzylaminomethyl- and substituted benzylaminomethyl-3-methoxy-17β-tosyloxyestra-1,3,5(10)-triene (3, 5a-k) do not undergo oxidation, but form a tetrahydrooxazin-2-one ring (7, 8a-k) via neighboring group p
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