Molecular Mechanics Calculations and the Stereochemical Course of Intramolecular Dipolar Cycloadditions of Nitrile Oxides

DOI: 10.1021/jo00256a030

Source and publish data:

Journal of Organic Chemistry p. 5063 - 5069 (1988)

Update date:2022-07-31

Topics: Intramolecular Stereochemical Nitrile oxides

Authors:

Hassner, Alfred

Murthy, K. S. Keshava

Padwa, Albert

Bullock, William H.

Stull, Paul D.

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Article abstract of DOI:10.1021/jo00256a030

The intramolecular nitrile oxide cycloaddition of a series of 4-vinyl N-substituted β-lactams has been investigated.The synthesis of the olefinic nitrile oxides involves treating a 4-vinylazetidinone with a dibromoalkane.The resulting bromo lactam was con

Full text of DOI:10.1021/jo00256a030

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