Einschiebung von Alkenen und Alkinen in die As-H-Bindungen von Cr(CO)5As(C6H5)H2

DOI: 10.1016/0022-328X(87)85192-6

Source and publish data:

Journal of Organometallic Chemistry p. 337 - 342 (1987)

Update date:2022-07-30

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Authors:

Frank, Lutz-R.

Jibril, Ibrahim

Zsolnai, Laszlo

Huttner, Gottfried

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Article abstract of DOI:10.1016/0022-328X(87)85192-6

The compound Cr(CO)5As(C6H5)H2 reacts with alkynes and alkenes under insertion into the As-H bonds to give Cr(CO)5 derivatives of vinyl or allyl substituted arsanes (1), respectively.Depending on the steric demand of the alkynes used, either one or both o

Full text of DOI:10.1016/0022-328X(87)85192-6

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