Ortho-Selective Side-Chain Nitration of Methyl-Substituted Alkenoylbenzenes and Its Application to Synthesis of 4-Nitro-1-tetralones

DOI: 10.1021/jo00278a011

Source and publish data:

Journal of Organic Chemistry p. 4034 - 4038 (1989)

Update date:2022-08-04

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Authors:

Keumi, Takashi

Inagaki, Toshihiko

Nakayama, Norihiro

Taniguchi, Masaaki

Morita, Toshio

Kitajima, Hidehiko

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Article abstract of DOI:10.1021/jo00278a011

Methyl-substituted alkenoylbenzenes 1a-m involving acryoyl, methacryloyl, β-(ethoxycarbonyl)acryloyl, crotonoyl, and cinnamoyl groups as alkenoyl functions reacted with fuming nitric acid in acetic anhydride to give 2-(nitromethyl)alkenoylbenzenes 2a-m in

Full text of DOI:10.1021/jo00278a011

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