COPPER CATALYZED REDUCTIVE METALLATION OF A PROPARGYLIC EPOXIDE TO AN ALLENYL LITHIUM REAGENT

DOI: 10.1016/S0040-4039(01)80407-X

Source and publish data:

Tetrahedron Letters p. 2391 - 2392 (1989)

Update date:2022-08-04

Topics:

Authors:

Alexakis, A.

Marek, I.

Mangeney, P.

Normant, J. F.

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Article abstract of DOI:10.1016/S0040-4039(01)80407-X

Phenethynyl cyclohexene oxide undergoes a reductive metallation by BuLi and catalytic amount of Cu^I salt.The resulting allenyl lithium reagent reacts, then, normally, with various electrophiles.

Full text of DOI:10.1016/S0040-4039(01)80407-X

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