Asymmetric Reactions of Thioacetals and Their S-Oxides Derived from 1,1'-Binaphthalene-2,2'-dithiol

DOI: 10.1021/jo00014a027

Source and publish data:

Journal of Organic Chemistry p. 4467 - 4473 (1991)

Update date:2022-08-04

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Authors:

Delogu, Giovanna

Lucchi, Ottorino De

Maglioli, Paola

Valle, Giovanni

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Article abstract of DOI:10.1021/jo00014a027

The chiral dithiepine 3 was selectively oxidized to all possible oxides: the sulfoxide 9, the sulfone 16, the sulfone-sulfoxide 20, the disulfoxide 21, and the disulfone 22.The sulfinyl oxygens of 9, 14, 20, and 21 are always in the pseudoaxial configurat

Full text of DOI:10.1021/jo00014a027

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